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Photochemistry with Quantum Optics from a Non-Adiabatic Quantum Trajectory Perspective
Chem ( IF 23.5 ) Pub Date : 2020-01-09 , DOI: 10.1016/j.chempr.2019.12.025
Felipe Herrera

Strong light-matter interaction with confined electromagnetic fields has emerged as a potential route to manipulate chemical reactivity and dynamics even in the absence of laser driving. In this issue of Chem, Fregoni et al. predict that the isomerization quantum yields of azobenzene can be enhanced inside a plasmonic nanocavity in comparison with free space, by performing a realistic non-adiabatic quantum trajectory study that does not neglect photonic dissipation. This prediction contradicts previous model calculations and thus may stimulate further experimental work.



中文翻译:

非绝热量子轨迹视角下的量子光学光化学

即使在没有激光驱动的情况下,与有限电磁场的强光物质相互作用也已成为控制化学反应性和动力学的潜在途径。在本期《化学》杂志中,Fregoni等人。预测通过进行不忽略光子耗散的现实的非绝热量子轨迹研究,与自由空间相比,等离激元纳米腔内偶氮苯的异构化量子产率可以提高。该预测与先前的模型计算相矛盾,因此可能会刺激进一步的实验工作。

更新日期:2020-01-09
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