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Enhanced high temperature microwave absorption of La0.9Sr0.1MnO3/MgAl2O4 composite ceramics based on controllable electrical conductivity
Journal of the European Ceramic Society ( IF 5.7 ) Pub Date : 2020-01-08 , DOI: 10.1016/j.jeurceramsoc.2020.01.010
Hongyao Jia , Wancheng Zhou , Hanyi Nan , Chunhai Wang , Yuchang Qing , Fa Luo , Dongmei Zhu

The high temperature microwave absorbing efficiency (HTMAE) of xLa0.9Sr0.1MnO3/(1 − x)MgAl2O4 composite ceramics was investigated by studying the crystal structure, electrical conductivity, and permittivity. The crystal structure of La0.9Sr0.1MnO3 and MgAl2O4 were maintained, but the Mn3+ and Al3+ ions were exchanged with each other through doping. The conductivity and permittivity of the composite ceramics increased with the increase of La0.9Sr0.1MnO3 content and test temperature. When x = 0.36, the electrical conductivity in La0.9Sr0.1MnO3 significantly enhanced the microwave polarization of the composite ceramics at high temperature. According to transmission/reflection modelling, the composite ceramics with x = 0.24 showed excellent HTMAE near the optimal thickness of 1.8 mm. Although the optimal thickness of the composite with x = 0.36 was reduced to 1.1 mm, the HTMAE was seriously lessened due to an impedance mismatch. xLa0.9Sr0.1MnO3/(1 − x)MgAl2O4 are promising as thin and efficient microwave absorbing materials at high temperatures and the microwave permittivity can be further enhanced by adjusting the conductivity of La0.9Sr0.1MnO3.



中文翻译:

基于可控电导率的La 0.9 Sr 0.1 MnO 3 / MgAl 2 O 4复合陶瓷的增强高温微波吸收

通过研究晶体结构,电导率和介电常数,研究了xLa 0.9 Sr 0.1 MnO 3 /(1- x)MgAl 2 O 4复合陶瓷的高温微波吸收效率。维持La 0.9 Sr 0.1 MnO 3和MgAl 2 O 4的晶体结构,但通过掺杂使Mn 3+和Al 3+离子交换。随着La 0.9 Sr 0.1 MnO 3的增加,复合陶瓷的电导率和介电常数增大。含量和测试温度。当x = 0.36时,La 0.9 Sr 0.1 MnO 3中的电导率显着增强了复合陶瓷在高温下的微波极化。根据透射/反射模型,x = 0.24的复合陶瓷在1.8 mm的最佳厚度附近显示出极好的HTMAE。尽管x = 0.36的复合材料的最佳厚度减小到1.1 mm,但由于阻抗不匹配,HTMAE大大降低了。xLa 0.9 Sr 0.1 MnO 3 /(1- x)MgAl 2 O 4作为在高温下用作薄而有效的微波吸收材料的理想材料,通过调节La 0.9 Sr 0.1 MnO 3的电导率可以进一步提高微波介电常数。

更新日期:2020-01-08
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