Recently, synthetic efforts to prepare novel modified porphyrinoid skeletons have been an important area of research due to its promising applications in various fields ranging from material chemistry to life science. The formation of [14]triphyrin(2.1.1) as relatively new congeners among the porphyrinoids seems quite astonishing because porphyrin macrocyclic core itself is perturbed to afford a contracted structure retaining aromaticity, however, exhibiting fundamentally different properties compared to other members in the porphyrin family. Although [14]triphyrin(2.1.1) chemistry has been mentioned in the literature, an effort which exclusively focussed on the development of [14]triphyrin(2.1.1) was not made. In the current review, we focused on the recent advancement in the chemistry of [14]triphyrin(2.1.1) including its synthesis, structure, coordination chemistry, photophysical and electrochemical properties. A fundamental insight in the triphyrin chemistry has immense scope since the reactivity of the molecule is less explored other than using as a ligand to prepare a few metal complexes and coupling reactions. The present review will definitely add to the furtherance of the chemistry of [14]triphyrin(2.1.1).

近来，由于其在从材料化学到生命科学的各个领域中的有希望的应用，制备新的修饰的卟啉类骨架的合成努力已成为重要的研究领域。卟啉类化合物中较新的同类物[14] triphyrin（2.1.1）的形成似乎是令人惊讶的，因为卟啉大环核本身被扰乱以提供保持芳香性的收缩结构，但是，与卟啉中的其他成员相比，其表现出根本不同的性质。家庭。尽管文献中提到了[14] triphyrin（2.1.1）的化学反应，但并未专门致力于[14] triphyrin（2.1.1）的开发。在当前的审查中，我们集中于[14] triphyrin（2.1.1）化学的最新进展，包括其合成，结构，配位化学，光物理和电化学性能。由于没有像用作配体来制备一些金属配合物和偶联反应那样，对分子的反应性的探索较少，因此在三联蛋白化学中有一个基本的见识。本综述肯定会增加[14] triphyrin（2.1.1）的化学作用。