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Synthesis, spectroscopic characterization, one and two-photon absorption properties, and electrochemistry of truxene π-expanded BODIPYs dyes
Dyes and Pigments ( IF 4.5 ) Pub Date : 2020-01-07 , DOI: 10.1016/j.dyepig.2020.108183
Jian Yang , Hao Jiang , Nicolas Desbois , Guoliang Zhu , Claude P. Gros , Yuanyuan Fang , Frédéric Bolze , Shifa Wang , Hai-Jun Xu

A series of mono- and bis-BODIPY substituted truxene derivatives were synthesized by the Knoevenagel condensation reaction and were fully characterized by NMR and HRMS. The photophysical properties of these new dyes have been investigated by UV–vis absorption spectroscopy, steady-state as well as time-resolved fluorescence spectroscopy and two-photon excited spectroscopy. Their electrochemical properties were investigated using cyclic voltammetry. The new dyes exhibit excellent photophysical properties in red to near-infrared region, including large extinction coefficients and high fluorescence quantum yields in methylene chloride solutions. These truxene-BODIPY dyads and triads also exhibit remarkable two-photon absorption cross section σ2 up to 6000 GM at 800 nm.



中文翻译:

丁二烯π-膨胀BODIPYs染料的合成,光谱表征,一光子和二光子吸收性质以及电化学

通过Knoevenagel缩合反应合成了一系列单-和双-BODIPY取代的丁烯衍生物,并通过NMR和HRMS进行了全面表征。这些新染料的光物理性质已通过紫外可见吸收光谱,稳态以及时间分辨荧光光谱和双光子激发光谱进行了研究。使用循环伏安法研究了它们的电化学性能。新染料在红色至近红外区域显示出出色的光物理性质,包括大的消光系数和在二氯甲烷溶液中的高荧光量子产率。这些truxene-BODIPY成对层和三单元组也表现出显着的双光子吸收横截面σ 2在800纳米至6000 GM。

更新日期:2020-01-07
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