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A lithium-ion conductive Li1.5Al0.25Ga0.25Ti1.5(PO4)3 solid electrolyte for electrochemical device
Solid State Ionics ( IF 3.2 ) Pub Date : 2020-01-07 , DOI: 10.1016/j.ssi.2019.115212
Kengo Oda , Hiroaki Saitoh , Yuto Hoaki , Hayato Shimoda , Toyoki Hirao , Wataru Ichiyoshi , Satoko Takase , Youichi Shimizu

Lithium-ion solid electrolyte disc with high conductivity even at low temperature for electrochemical devices were designed using Li1+x+yAlxGayTi2-x-y(PO4)3 (x + y = 0–0.5) with NASICON-type structure. The solid-electrolyte discs were synthesized by a solution method at 900–1000 °C. Effects of Al and/or Ga dopants and crystal structures on ionic conductivity of the solid electrolytes were investigated. Almost single phase of Li1+x+yAlxGayTi2-x-y(PO4)3 (x + y = 0–0.5) systems could be synthesized at sintering temperatures above 900 °C up to x = 0.5, y = 0.25. An ionic conductivity as high as 9.3 × 104 S/cm at 30 °C and activation energy of 0.29 eV were obtained with the trivalent-cation double-doped Li1.5Al0.25Ga0.25Ti1.5(PO4)3 disc sintered at 900 °C.



中文翻译:

用于电化学装置的锂离子导电Li 1.5 Al 0.25 Ga 0.25 Ti 1.5(PO 43固体电解质

使用NASICON-使用Li 1 + x + y Al x Ga y Ti 2-xy(PO 43(x + y = 0-0.5)设计了即使在低温下也可用于电化学装置的具有高电导率的锂离子固体电解质盘。类型结构。固态电解质圆盘是通过在900–1000°C下的溶液法合成的。研究了Al和/或Ga掺杂剂和晶体结构对固体电解质离子电导率的影响。Li 1 + x + y Al x Ga y Ti 2-xy(PO 43的几乎单相(x + y = 0-0.5)系统可以在900°C以上的烧结温度下合成,最高x = 0.5,y = 0.25。的离子电导率高达9.3×10 - 4  S / cm的在30℃和0.29电子伏特的激活能,用三价阳离子双掺杂锂获得1.5的Al 0.250.25的Ti 1.5(PO 43光盘在烧结900℃。

更新日期:2020-01-07
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