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A responsive supramolecular-organic framework: Functionalization with organic laser dye and lanthanide ions for sensing of nitrobenzene
Journal of Solid State Chemistry ( IF 3.3 ) Pub Date : 2020-01-07 , DOI: 10.1016/j.jssc.2020.121171
Danyong Jiang , Huaifang Fang , Gang Li , Guoli Zheng

A anionic supramolecular-organic framework, namely [(NH4)4·[Zn (bpdo)3]2·[Zn(bpdo)2·2H2O]·[(p-sulfonatocalix[4]arene)2]·H2O SOF-1 has been synthesized, which exhibited highly efficient adsorption of organic laser dye (4-[p-(dimethylamino)styryl] -1-methylpyridinium, DSM). In addition, we prepared a responsive luminescent Eu3+@ SOF-1 by postsynthetic incorporation of Eu3+ cations into the SOF-1 framework, which can serve as a platform for the recognitions of nitrobenzene.



中文翻译:

反应灵敏的超分子-有机框架:有机激光染料和镧系离子的官能化,用于硝基苯的检测

阴离子超分子有机骨架,即[(NH 44 ·[Zn(bpdo)3 ] 2 ·[Zn(bpdo)2 ·2H 2 O]·[(对-磺基对杯[4]芳烃)2 ]·H合成了2 O SOF-1,它具有对有机激光染料(4- [对-(二甲基氨基)苯乙烯基] -1-甲基吡啶鎓,DSM)的高效吸附。此外,我们通过将Eu 3+阳离子后合成地掺入SOF-1骨架中,制备了响应性发光Eu 3+ @ SOF-1 ,它可以作为识别硝基苯的平台。

更新日期:2020-01-07
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