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Tuning the stability of organic radicals: from covalent approaches to non-covalent approaches
Chemical Science ( IF 9.556 ) Pub Date : 2020-01-04 , DOI: 10.1039/c9sc06143f
Bohan Tang; Jiantao Zhao; Jiang-Fei Xu; Xi Zhang

Organic radicals are important species with single electrons. Because of their open-shell structure, they are widely used in functional materials, such as spin probes, magnetic materials and optoelectronic materials. Owing to the high reactivity of single electrons, they often serve as a key intermediate in organic synthesis. Therefore, tuning the stability of radicals is crucial for their functions. Herein, we summarize covalent and non-covalent approaches to tune the stability of organic radicals through steric effects and tuning the delocalization of spin density. Covalent approaches can tune the stability of radicals effectively and non-covalent approaches benefit from dynamicity and reversibility. It is anticipated that the further development of covalent and non-covalent approaches, as well as the interplay between them, may push the fields forward by enriching new radical materials and radical mediated reactions.
更新日期:2020-01-14

 

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