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Chemiluminescence of 3-aminophthalic acid anion-hydrogen peroxide-cobalt (II).
Luminescence ( IF 2.9 ) Pub Date : 2020-01-03 , DOI: 10.1002/bio.3740
Kai Huang 1 , Yonghua Sun 1 , Lin Liu 2 , Chaoyu Hu 1
Affiliation  

The 3-aminophthalic acid anion is a light emitter in luminol chemiluminescence. In the present study, the chemiluminescence of the 3-aminophthalic acid anion itself in the presence of hydrogen peroxide-cobalt (II) was studied. The results indicated that 3-aminophthalic acid anion is highly chemiluminescent in the typical hydrogen peroxide-cobalt (II) system. The peak wavelength of this chemiluminescence and the kinetic profile of the 3-aminophthalic acid anion-hydrogen peroxide-cobalt (II) reaction showed similarity with that of luminol, but the chemiluminescence of 3-aminophthalic acid anion had a much lower background signal. In addition, the chemiluminescence mechanism of 3-aminophthalic acid anion-hydrogen peroxide-cobalt (II) was also discussed and speculated as the interaction between 3-aminophthalic acid anion and singlet oxygen.

中文翻译:

3-氨基邻苯二甲酸阴离子-过氧化氢-钴(II)的化学发光。

3-氨基邻苯二甲酸阴离子是鲁米诺化学发光中的发光体。在本研究中,研究了在过氧化氢-钴(II)存在下3-氨基邻苯二甲酸阴离子本身的化学发光。结果表明,3-氨基邻苯二甲酸阴离子在典型的过氧化氢-钴(II)体系中具有高度化学发光性。该化学发光的峰值波长和3-氨基邻苯二甲酸阴离子-过氧化氢-钴(II)反应的动力学曲线显示出与鲁米诺的相似性,但是3-氨基邻苯二甲酸阴离子的化学发光具有低得多的背景信号。此外,还讨论了3-氨基邻苯二甲酸阴离子-过氧化氢-钴(II)的化学发光机理,并推测是3-氨基邻苯二甲酸阴离子与单线态氧之间的相互作用。
更新日期:2020-04-03
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