Abstract In this study, 3-ferrocenyl substituted cyclooctene (3FcCOE) monomer was synthesized and polymerized via the ring-opening metathesis polymerization (ROMP). The poly(3FcCOE) exhibited remarkably high head-to-tail regioregularity and high trans-stereoregularity. Diblock coplymer and triblock terpolymers were then synthesized by copolymerization of 3FcCOE with norbornene and N-methylnorbornene-5,6-dicarboximid. The monomers and polymers were characterized by 1H NMR and 13C NMR. The molecular weight and PDI of the polymers were determined by GPC. Moreover, electrochemical, DSC and tensile property tests of the various polymers were also show that they have unique physical properties.

中文翻译：

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3-二茂铁取代环辛烯的区域选择性和立体选择性开环复分解聚合以及与降冰片烯衍生物的共聚

摘要 本研究通过开环易位聚合（ROMP）合成并聚合了3-二茂铁基取代的环辛烯（3FcCOE）单体。聚（3FcCOE）表现出非常高的头对尾区域规则性和高反立体规则性。然后通过 3FcCOE 与降冰片烯和 N-甲基降冰片烯-5,6-二甲酰亚胺的共聚合成二嵌段共聚物和三嵌段三元共聚物。单体和聚合物通过1H NMR和13C NMR表征。聚合物的分子量和 PDI 由 GPC 测定。此外，各种聚合物的电化学、DSC和拉伸性能测试也表明它们具有独特的物理性能。