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Mixed n-type electronic, oxide ion, and protonic conduction in In-doped SrTi1-xRuxO3-δ
Journal of Solid State Chemistry ( IF 3.3 ) Pub Date : 2020-01-03 , DOI: 10.1016/j.jssc.2019.121164
Chan Young Park , Jiho Yoo , Sung-Chan Nam , Allan J. Jacobson

As part of a study of mixed n-type electronic and ionic conductors, the conductivities of indium doped strontium ruthenium titanates were determined. The SrTi1-x-yRuxInyO3-δ (x = 0.1–0.4, y = 0–0.2) compositions were prepared by conventional solid-state synthesis. Samples were determined to be of a single phase by X-ray powder diffraction and electron probe microanalysis. The temperature and pO2 dependences of the electrical conductivities were investigated by using DC and AC four-probe methods. STRIO820 and STRIO640 have conductivity of 6.4 and 5.4 Scm−1, respectively, at 900 °C and pO2 = 1 atm. The conductivities of the In-doped samples under the same conditions were lower than that of SrTi1-xRuxO3-δ by around two orders of magnitude. For STRIO622, when pO2 was increased from 10−4 to 1 atm, the DC conductivities decreased, indicating n-type conduction. The pO2 dependence of conductivity was analyzed using the relation σT = ApO21/x + σi. STRIO622 shows significant ionic conductivity, with σi ∼0.21 Scm−1 at 1000 °C. The DC conductivities of STRIO622 in reducing environments (5% H2/N2 saturated with water) show protonic conduction at low temperatures. The thermal expansion coefficients (TECs) were ∼8.9–11.2 × 10−6 K−1 at 200 ≤ T ≤ 990 °C.



中文翻译:

In掺杂SrTi 1-x Ru x O3 -δ中的混合n型电子,氧化物离子和质子传导

作为混合n型电子和离子导体研究的一部分,确定了铟掺杂锶钌钛酸盐的电导率。通过传统的固态合成方法制备了SrTi 1-xy Ru x In y O3 (x = 0.1-0.4,y = 0-0.2)组合物。通过X射线粉末衍射和电子探针显微分析确定样品为单相。通过使用直流和交流四探针方法研究了温度和电导率与pO 2的关系。STRIO820和STRIO640在900°C和pO 2下的电导率分别为6.4和5.4 Scm -1 = 1个大气压。在相同条件下,In掺杂样品的电导率比SrTi 1-x Ru x O3 的电导率低两个数量级。对于STRIO622,当pO 2从10 -4增加到1 atm时,直流电导率降低,表明为n型导通。在PO 2使用下面的关系进行分析的导电性依赖σ Ť  = APO 2 1 / X  +  σ。STRIO622节目显著离子传导性,与σ~0.21 SCM -1在1000℃。还原环境中STRIO622的直流电导率(5%H2 / N 2用水饱和)在低温下表现出质子传导。在200≤T≤990  °C的条件下,热膨胀系数(TECs)约为8.9-11.2×10 -6  K -1

更新日期:2020-01-04
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