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Chiral metal-organic porous materials: synthetic strategies and applications in chiral separation and catalysis.
Topics in Current Chemistry ( IF 8.6 ) Pub Date : 2010-01-01 , DOI: 10.1007/128_2009_7
Kimoon Kim 1 , Mainak Banerjee , Minyoung Yoon , Sunirban Das
Affiliation  

In the light of growing demand for chiral purity in biological and chemical processes, the synthesis of chiral metal-organic porous materials (CMOPMs) have become immensely important because of their potential applications in chiral separation and asymmetric catalysis. In this chapter, the synthetic strategies for CMOPMs are discussed briefly keeping the focus on their applications. Two distinct approaches have been taken to synthesize a wide variety of chiral structures with different topologies and accessible cavities. Several CMOPMs have shown catalytic activity and enantioselectivity toward a number of chemical transformations. On many occasions, the chiral pores of the MOPMs have been utilized in order to achieve separation of enantiomers from racemates. Recent applications of homochiral MOPMs in heterogeneous asymmetric catalysis and chiral separations are also presented here.

中文翻译:

手性金属有机多孔材料:合成策略及其在手性分离和催化中的应用。

鉴于生物和化学过程中对手性纯度的需求不断增长,手性金属有机多孔材料(CMOPM)的合成已变得极为重要,因为它们在手性分离和不对称催化中的潜在应用。在本章中,将简要讨论CMOPM的综合策略,并将重点放在其应用上。已经采取了两种不同的方法来合成具有不同拓扑结构和可访问空腔的多种手性结构。几种CMOPM表现出对许多化学转化的催化活性和对映选择性。在许多情况下,已利用MOPM的手性孔来实现对映体与外消旋物的分离。
更新日期:2019-11-01
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