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Isolation, Structural Assignment of Isoselagintamarlin A from Selaginella tamariscina and Its Biomimetic Synthesis.
Natural Products and Bioprospecting Pub Date : 2019-01-03 , DOI: 10.1007/s13659-018-0195-5 Qin-Feng Zhu 1, 2 , Li-Dong Shao 1 , Xing-De Wu 1 , Jiang-Xin Liu 1 , Qin-Shi Zhao 1
中文翻译:
卷柏卷柏中异黄藻素A的分离,结构分配及其仿生合成。
更新日期:2019-01-03
Natural Products and Bioprospecting Pub Date : 2019-01-03 , DOI: 10.1007/s13659-018-0195-5 Qin-Feng Zhu 1, 2 , Li-Dong Shao 1 , Xing-De Wu 1 , Jiang-Xin Liu 1 , Qin-Shi Zhao 1
Affiliation
Abstract
Isoselagintamarlin A (1), a selaginellin analogue featured a rare benzofuran unit, was isolated from Selaginella tamariscina. Its complete structural assignment was established through a combination of high-field NMR technique and biomimetic synthesis. Notably, isoselagintamarlin A (1) was successfully synthesized via sequential oxidations and intramolecular cyclization.Graphical Abstract
中文翻译:
卷柏卷柏中异黄藻素A的分离,结构分配及其仿生合成。