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Preparation and application of a novel electrochemical sensing material based on surface chemistry of polyhydroquinone.
Biomaterials Advances ( IF 7.9 ) Pub Date : 2014-03-26 , DOI: 10.1016/j.msec.2014.03.039
Xueping Dang 1 , Yingkai Wang 2 , Chengguo Hu 3 , Jianlin Huang 4 , Huaixia Chen 4 , Shengfu Wang 4 , Shengshui Hu 3
Affiliation  

A new analogue of polydopamine (PDA), i.e., polyhydroquinone (PH2Q), was polymerized and its surface chemistry was studied by different ways of characterization. PH2Q was produced by the self-polymerization of H2Q mediated by dissolved oxygen, and the self-polymerization process was strongly dependent on the type and the pH value of the buffer solutions. PH2Q can not only achieve surface hydrophilization of different substrates like polyethylene terephthalate (PET) film, graphite strip, C12SH/Au and wax slice, but also possess several unique properties like reversible adsorption, good solubility and low cost. These properties made PH2Q an ideal polymeric modifier for the noncovalent functionalization of some nanomaterials. By simply grinding with PH2Q, pristine multi-walled carbon nanotubes (MWNTs) can be readily dispersed in water with high solubility and good stability. The resulting MWNT–PH2Q composite exhibited excellent electrochemical performance, which was employed for the simultaneous determination of dopamine (DA) and uric acid (UA).



中文翻译:

基于聚氢醌表面化学的新型电化学传感材料的制备与应用。

聚合了一种新的聚多巴胺(PDA)类似物,即聚氢醌(PH 2 Q),并通过不同的表征方法研究了其表面化学。PH 2 Q是由溶解氧介导的H 2 Q自聚合产生的,自聚合过程在很大程度上取决于缓冲溶液的类型和pH值。PH 2 Q不仅可以实现聚对苯二甲酸乙二醇酯(PET)薄膜,石墨带,C 12 SH / Au和蜡切片等不同基材的表面亲水化,而且还具有可逆吸附,良好的溶解性和低成本等多种独特性能。这些特性使PH 2Q是某些纳米材料非共价官能化的理想聚合物改性剂。通过简单地用PH 2 Q研磨,原始的多壁碳纳米管(MWNT)可以很容易地以高溶解度和良好的稳定性分散在水中。所得的MWNT-PH 2 Q复合材料表现出优异的电化学性能,可用于同时测定多巴胺(DA)和尿酸(UA)。

更新日期:2014-03-26
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