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Alkali-metal ion/molecule association reactions and their applications to mass spectrometry
Mass Spectrometry Reviews ( IF 6.6 ) Pub Date : 2000-07-21 , DOI: 10.1002/1098-2787(200005/06)19:3<111::aid-mas1>3.0.co;2-k
Fujii 1
Affiliation  

This review will be concerned primarily with thermal alkali-metal ion association reactions of the general type: A+ + M + N reversible (A + M)+ + N. Where A denotes a positively charged alkali metal ion, M is neutral species and N works as a third body. As indicated, most association reactions are reversible, and the A-M bond derives primarily from electrostatic forces whose energy (affinity) is typically 50 kcal/mol or less, often much less. The review includes reaction mechanism, instrumentation, and application to mass spectrometry, together with reaction rates and alkali ion affinities of the classified compounds.

中文翻译:

碱金属离子/分子缔合反应及其在质谱中的应用

这篇综述主要涉及一般类型的热碱金属离子缔合反应:A + + M + N可逆(A + M)+ +N。其中A表示带正电的碱金属离子,M是中性物质,N作为第三体。如图所示,大多数缔合反应是可逆的,并且AM键主要来自静电力,其能量(亲和力)通常为50 kcal / mol或更低,通常更低。综述包括反应机理,仪器和在质谱中的应用,以及分类化合物的反应速率和碱离子亲和力。
更新日期:2019-11-01
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