Abstract

Cationic cobaltocenium-containing polyelectrolytes have a unique ability to form ionic complex with various anionic species. We carried out two sets of model study to compare the relative binding strength of a cobaltocenium-containing polyelectrolyte. First, the nature and relative strength of intermolecular interaction between cobaltocenium-containing polyelectrolytes and different anionic probes were investigated by spectroscopic methods. A dye-displacement method was used to monitor absorbance and fluorescence emissions. Second, the binding strength of this cobaltocenium-containing polyelectrolyte was compared with a classical quaternary ammonium polymer. Formation of polyelectrolyte complex between the cobaltocenium-containing polyelectrolyte and a common anionic polyelectrolyte at various concentrations was examined by optical absorption and light scattering.

Graphical Abstract

中文翻译：

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含钴ce的聚电解质与阴离子探针的结合。

抽象的

含阳离子钴ce的聚电解质具有与各种阴离子物质形成离子络合物的独特能力。我们进行了两组模型研究，以比较含钴ce的聚电解质的相对结合强度。首先，通过光谱方法研究了含钴ce的聚电解质与不同阴离子探针之​​间的分子间相互作用的性质和相对强度。染料置换法用于监测吸光度和荧光发射。其次，将该含钴ce的聚电解质的结合强度与经典的季铵聚合物进行了比较。

图形概要