GRAPHICAL ABSTRACT ABSTRACT A new reaction of elemental phosphorus (P4) with elemental sulfur and 1,3-propylene glycol in the presence of different amines has been investigated. Ammonium salts of O,O'-alkylenedithiophosphoric acids have been observed as main products of the reaction. Octathiotetraphosphetane ammonium salts were formed as minor products. The reaction is characterized by a complete conversion of white phosphorus and is not accompanied by the release of hydrogen sulfide. The crystal structure features's of diethylammonium salt of O,O'-propylenedithiophosphoric acid were determined using single crystal X-ray diffraction. Piperidinium salt of octathiotetraphosphetane in DMSO and DMF solutions possess significant antifungal activity against Candida albicans.

中文翻译：

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合成O,O'-亚烷基二硫代磷酸和八硫代四磷酸铵盐的新方法。O,O'-亚丙基二硫代磷酸二乙基铵盐的晶体结构特征

图形摘要 摘要 已经研究了元素磷 (P4) 与元素硫和 1,3-丙二醇在不同胺存在下的新反应。已观察到 O,O'-亚烷基二硫代磷酸的铵盐是该反应的主要产物。八硫代四磷酸铵盐作为次要产物形成。该反应的特点是白磷完全转化，不伴随硫化氢的释放。使用单晶X射线衍射测定了O,O'-亚丙基二硫代磷酸二乙基铵盐的晶体结构特征。DMSO 和 DMF 溶液中的八硫代四磷酸哌啶盐对白色念珠菌具有显着的抗真菌活性。