Phosphorus (P) is an indispensable element for all life on Earth and, during the past decade, concerns about the future of its global supply have stimulated much research on soil P and method development. This review provides an overview of advanced state-of-the-art methods currently used in soil P research. These involve bulk and spatially resolved spectroscopic and spectrometric P speciation methods (1 and 2D NMR, IR, Raman, Q-TOF MS/MS, high resolution-MS, NanoSIMS, XRF, XPS, (µ)XAS) as well as methods for assessing soil P reactions (sorption isotherms, quantum-chemical modeling, microbial biomass P, enzymes activity, DGT, 33P isotopic exchange, 18O isotope ratios). Required experimental set-ups and the potentials and limitations of individual methods present a guide for the selection of most suitable methods or combinations.

中文翻译：

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土壤磷研究的创新方法：综述

磷 (P) 是地球上所有生命不可或缺的元素，在过去十年中，对其全球供应未来的担忧激发了对土壤 P 和方法开发的大量研究。本综述概述了目前用于土壤磷研究的先进方法。这些涉及本体和空间分辨光谱和光谱 P 形态形成方法（1 和 2D NMR、IR、拉曼、Q-TOF MS/MS、高分辨率 MS、NanoSIMS、XRF、XPS、（μ）XAS）以及用于评估土壤磷反应（吸附等温线、量子化学模型、微生物生物量磷、酶活性、DGT、33P 同位素交换、18O 同位素比）。所需的实验设置以及个别方法的潜力和局限性为选择最合适的方法或组合提供了指导。