当前位置 : X-MOL首页行业资讯 › RSC主编推荐:有机领域精彩文章快览(免费阅读原文)

RSC主编推荐:有机领域精彩文章快览(免费阅读原文)

英国皇家化学会(RSC)是一个超过175年历史的面向全球化学家的非营利会员制机构,旗下拥有44种期刊,其中很多在化学领域有很高影响力。为了进一步帮助广大读者追踪科技前沿热点,X-MOL团队与英国皇家化学会合作,推出英国皇家化学会期刊主编推荐的精彩文章快览,本期文章属“有机领域”,英文点评来自英国皇家化学会期刊的主编。如果大家对我们的解读有更多的补充和点评,欢迎在文末写评论发表您的高见!


Chemical Science (IF: 9.556)



1. Enantioselective palladium/copper-catalyzed C–C σ-bond activation synergized with Sonogashira-type C(sp3)–C(sp) cross-coupling alkynylation

Chem. Sci., 2019, Advance Article

DOI: 10.1039/C9SC02431J



Researchers in China have reported a new enantioselective palladium/copper-catalyzed alkyl alkynylation of cyclobutanones with terminal alkynes via Suzuki coupling reactions to make indanones bearing an alkyne moiety and a quaternary carbon stereocentre. They synthesised a variety of TADDOL-derived phosphoramidite ligands (TFSi-Phos) to efficiently regulate the stereoselectivity of the reaction.


Open Access(可免费阅读原文)

扫描或长按二维码,识别后直达原文页面,或点此查看原文


2. Practical, Metal-Free Remote Heteroarylation of Amides via Unactivated C(sp3)-H Bond Functionalization

Chem. Sci., 2019, Advance Article

DOI: 10.1039/C9SC02564B



Scientists in China have disclosed a new metal-free method for the heteroarylation of amides using visible light. The reaction scope is large and is carried out under neutral conditions. This C-H bond functionalisation reaction could be used to make molecules of medicinal importance in the future.


Open Access(可免费阅读原文)

扫描或长按二维码,识别后直达原文页面,或点此查看原文


Organic Chemistry Frontiers (IF: 5.076)



1. Creation of bispiro[pyrazolone-3,3′-oxindoles] via a phosphine-catalyzed enantioselective [3+2] annulation of the Morita–Baylis–Hillman carbonates with pyrazoloneyldiene oxindoles

Org. Chem. Front., 2019, Advance Article

DOI: 10.1039/C9QO00471H


A [3+2] annulation between the Morita–Baylis–Hillman (MBH) carbonates and pyrazoloneyldiene oxindoles catalyzed by (S)-SITCP has been developed. Structurally novel bispiro[pyrazolone-3,3′-oxindoles] containing two contiguous quaternary stereogenic centers were created in excellent yields, in a diastereospecific and highly enantioselective manner.


限时免费阅读原文,登录后可下载

扫描或长按二维码,识别后直达原文页面,或点此查看原文


2. Bistrifluoromethylated organocuprate [Ph4P]+[Cu(CF3)2]: synthesis, characterization and its application for trifluoromethylation of activated heteroaryl bromides, chlorides and iodides

Org. Chem. Front., 2019, Advance Article

DOI: 10.1039/C9QO00527G


The synthesis and characterization of a bistrifluoromethylated organocuprate [Ph4P]+[Cu(CF3)2] and its reactions with a variety of activated heteroaryl bromides, chlorides and iodides were described. These results showed that complex [Ph4P]+[Cu(CF3)2] can serve as a trifluoromethylating reagent.


限时免费阅读原文,登录后可下载

扫描或长按二维码,识别后直达原文页面,或点此查看原文


如果篇首注明了授权来源,任何转载需获得来源方的许可!如果篇首未特别注明出处,本文版权属于 X-MOLx-mol.com ), 未经许可,谢绝转载!

LANGMUIR
Drug Delivery 给药系统
SN Applied Sciences期刊征稿
Discover Sustainability特刊征稿
绿色化学跨学科研究方法
农用化学品对水质影响合集征稿
Frontiers招聘
Virulence
化学循环燃烧及其他
低碳能源系统自主协同运行
食品化学食品技术
等离子体驱动气相沉积工艺
化学科学的最新进展
默克化学品
Nature Portfolio
最新物联网研究成果
生态材料最新进展合集征稿中
APPLIED新
极地科学专辑
Physics
scientific reports
APPLIED
organic materials
欢迎新作者ACS
中国作者高影响力研究精选
虚拟特刊
屿渡论文,编辑服务
浙大
上海中医药
南科大
密西根
西湖大学
华东师范
华东师范
江南大学
深圳湾实验室
美国
新加坡国立大学
深圳湾
香港城市大学
深圳湾实验室
隐藏1h前已浏览文章
课题组网站
新版X-MOL期刊搜索和高级搜索功能介绍
ACS材料视界
天合科研
x-mol收录
试剂库存
down
wechat
bug