杨贯文 理学博士 研究员 博士生导师

浙江理工大学材料科学与工程学院

教育和工作经历

2023.03-2025.01 浙江大学，高分子科学与工程学系，副研究员

2020.10-2023.02 浙江大学，高分子科学与工程学系，博士后

2017.09-2020.09 浙江大学，高分子化学与物理，博士

2016.04-2017.08 浙江大学，高分子科学与工程学系，研究助理

2013.10-2016.01 山东威智医药工业有限公司，生产部，中试组长

2010.09-2013.06 大连理工大学，有机化学，硕士

2006.09-2010.06 济南大学，化学工程与工艺，学士

主要研究方向和成果

主要从事仿酶催化可降解高分子创制、碳一气体的催化转化等研究。以第一作者或通讯作者在Chem. Rev.、Acc. Chem. Res.、Nat. Synth.、J. Am. Chem. Soc. (3)、Angew. Chem. Int. Ed. (4)、Macromolecules (4)等期刊发表研究和综述论文25篇。授权国家发明专利9项、美国发明专利1项。主持国家自然科学基金、中国博士后基金等项目。

代表性论文

1. 1.Xie, D.; Jia, Z.-H.; Zhang, Y.-L.; Cai, X.-L.; Liu, L.-N.; Yang, G.-W.*; Kang, X.*; Zhang, X.; Zhang, Y.-Y.*, Switchable Polymerization from Monomer Mixtures to Synthesize Oxygen-Rich Block Copolymers with Dual Recyclability and Degradability. Angew. Chem. Int. Ed. 2025, e202424856.

2. 2.Chen, Zhiyu.;Yang, Guan-Wen.*;Wu, Tianhao.;Qian, Zizhao.;Wu, Guang-Peng.*,Dual Kinetic Control of Polycarbonate Sequences via Breaking Catalysis Symmetry Using Dual Biomimetic Organoboron Catalysts.Macromolecules 2025, 58, 3, 1349-1356.

3. 3.Yang, G.-W.; Xie, R.; Zhang, Y.-Y.; Xu, C-K.; Wu, G.-P.*, Evolution of Copolymers of Epoxides and CO₂: Catalysts, Monomers, Architectures, and Applications. Chem. Rev. 2024, 124, 12305–12380.

4. 4.Xu, C-K.; Lu, C.; Zhao, S.; Yang, G.-W.*; Li, W.; Wang, J.; Wu, G.-P.*, Rational Optimization of Ammonium and Phosphonium Cations of Bifunctional Organoborane Catalysts for Copolymerization of Propylene Oxide with CO₂ to Afford Poly(propylene carbonate). Macromolecules 2024, 57, 9076–9087.

5. 5.Xie, R.; Wang, Y.; Li, S.; Li, B.; Xu, J.; Liu, J.; He, Y.; Yang, G.-W.*; Wu, G.-P.*, Insights into the Distinct Behaviors between Bifunctional and Binary Organoborane Catalysts through Terpolymerization of Epoxide, CO₂, and Anhydride. Angew. Chem. Int. Ed. 2024, 63, e202404207.

6. 6.Yang, G.-W.; Xu, C-K.; Xie, R.; Zhang, Y.-Y.; Lu, C.; Qi, H.; Yang, L.; Wang, Y.; Wu, G.-P.*, Precision Copolymerization of CO₂ and Epoxides Enabled by Organoboron Catalysts. Nat. Synth. 2022, 1, 892−901.

7. 7.Zhang, Y.-Y.; Yang, G.-W.*; Xie, R.; Zhu. X-F.; Wu, G.-P.*, Sequence-Reversible Construction of Oxygen-Rich Block Copolymers from Epoxide Mixtures by Organoboron Catalyst, J. Am. Chem. Soc. 2022, 144, 19896–19909.

8. 8.Yang, G.-W.^#; Wang, Y.^#; Qi, H.; Zhang, Y.-Y.; Zhu, X-F.; Lu, C.; Yang, L.; Wu, G.-P.*, Exclusive Preparation and Depolymerization of Chemically Recyclable CO₂ Plastics Enabled by Dinuclear Organoboron Catalysts. Angew. Chem. Int. Ed. 2022, 61, e202210243.

9. 9.Qi, H.; Xie, R.; Yang, G.-W.*; Zhang, Y.-Y.; Xu, C.-K.; Wang, Y.; Wu, G.-P.*, Rational Optimization of Bifunctional Organoboron Catalysts for Efficient Ring-Opening Polymerization of Epoxides, Macromolecules 2022, 55, 9081–9090.

10. 10.Yang, G.-W.; Zhang, Y.-Y.; Wu, G.-P.*, Modular Organoboron Catalysts Enable Transformations with Unprecedented Reactivity. Acc. Chem. Res. 2021, 54, 4434−4448.

11. 11.Yang, G.-W.; Xu, C.-K.; Xie, R.; Zhang, Y.-Y.; Zhu, X.-F., Wu, G.-P.*, Pinwheel-Shaped Tetranuclear Organoboron Catalysts for Perfectly Alternating Copolymerization of CO₂ and Epichlorohydrin. J. Am. Chem. Soc. 2021, 143, 3455–3465.

12. 12.Yang, G.-W.; Zhang, Y.-Y.; Xie, R.; Wu, G.-P.*, Scalable Bifunctional Organoboron Catalysts for Copolymerization of CO₂ and Epoxides with Unprecedented Efficiency. J. Am. Chem. Soc. 2020, 142, 12245–12255.

13. 13.Yang, G.-W.^#; Zhang, Y.-Y.^#; Xie, R.; Wu, G.-P.*, High‐Activity Organocatalysts for Polyether Synthesis via Intramolecular Ammonium Cation Assisted S_N2 Ring‐Opening Polymerization. Angew. Chem. Int. Ed. 2020, 59, 16910–16917.

14. 14.Yang, G.-W.; Zhang, Y.-Y.; Wang, Y.-Y.; Wu, G.-P.*; Xu, Z.-K.; Darensbourg, D. J.*, Construction of Autonomic Self-Healing CO₂-Based Polycarbonates via One-Pot Tandem Synthetic Strategy. Macromolecules 2018, 51, 1308–1313.

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