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邵英博(泰达投资控股) 博士研究生    

邵英博,男,汉族,中共党员,19973月出生于天津市。20159-20196月攻读南开大学化学学士学位,20199-20216月攻读南开大学有机化学硕士学位(导师:薛小松 研究员),20219-20256月转攻南开大学有机化学博士学位(导师:程津培 教授、薛小松 研究员)。

 

在学期间共发表19篇学术论文,其中第一作者(含共一)7篇:

[1]   Shao, Y.; Xu, H.; et al. Machine Learning-Based Prediction of Bond Dissociation Energies for Metal-Trifluoromethyl Compounds. Chin. J. Chem. 2025, 43, 1363. (第一作者)

[2]   Shao, Y.; Ren, Z.; et al. Computational Insights into the Reactivity Difference between Hypervalent Bromine(III) and Hypervalent Iodine(III) Reagent in the C-H Amination and Alkene Aziridination. Adv. Synth. Catal. 2023365, 2737. (第一作者)

[3]   Shao, Y.#; Ren, Z.#; et al. Predicting bond dissociation energies of cyclic hypervalent halogen reagents using DFT calculations and graph attention network model. Beilstein J. Org. Chem. 202420, 1444. (共同第一作者)

[4]   Dong, X.#Shao, Y.#; et al. Radical 6-Endo Addition Enables Pyridine Synthesis under Metal-Free Conditions. Angew. Chem. Int. Ed. 2024, e202410297. (共同第一作者)

[5]   Wang, D.#Shao, Y.#; et al. Enantioselective Synthesis of Planar-Chiral Macrocycles through Asymmetric Electrophilic Aromatic Amination. Angew. Chem. Int. Ed. 202261, e2022010. (共同第一作者)

[6]   Zhou, X.-Y.#Shao, Y.#; et al. B(C6F5)3-Catalyzed C(sp3)–H Alkylation of Tertiary Amines with Electron-Deficient Olefins: Determinants of Site Selectivity. ACS Catal. 202414, 8041. (共同第一作者)

[7]   Zhang, D.#Shao, Y.#; et al. Remote Enantioselective Desymmetrization of 9,9-Disubstituted 9,10-Dihydroacridines through Asymmetric Aromatic Aminations. ACS Catal. 202212, 14609. (共同第一作者)

[8]   Li, C.; Shao, Y.; et al. Enantioselective synthesis of chiral quinohelicenes through sequential organocatalyzed Povarov reaction and oxidative aromatization. Nat. Commun. 202314, 3380. (第二作者)

[9]   Lin, W.; Shao, Y.; et al. Enantioselective Synthesis of “NO2···NH” Hydrogen Bond-Stabilized C–N Axially Chiral Diarylamines. ACS Catal. 202414, 1183. (第二作者)

[10] Ge, Y.; Shao, Y.; et al. Distal Amidoketone Synthesis Enabled by Dimethyl Benziodoxoles via Dual Copper/Photoredox Catalysis. ACS Catal. 202313, 3749. (第二作者)

[11] Pan, Y.-L.; Shao, Y.; et al. Kinetic Resolution of 2H‑Azirines by Asymmetric Allylation Reactions. ACS Catal. 202111, 13752. (第二作者)

[12] Wang, Y.; Shao, Y.; et al. Incorporation of germanium into amines via deoxygenative germylation of aromatic amides with hydrogermanes. Cell Rep. Phys. Sci. 20223, 101116. (第二作者)

[13] Pan, Y.-L.; Shao, Y.; et al. Asymmetric difluorocarbonylation reactions of non-active imines catalyzed by Bi(OAc)3/chiral phosphoric acid. Org. Chem. Front. 2022, 9, 3990. (第二作者)

[14] Pan, M.; Shao, Y.; et al. Asymmetric Synthesis of N-N Axially Chiral Compounds by Phase Transfer-Catalyzed Alkylations. Org. Lett. 202224, 374. (第二作者)

[15] Zhang, J.; Shao, Y.; et al. Transition State Stabilization by SCF2-H···O Bifurcated Hydrogen Bond. Chem. Asian J. 2023, e202201244. (第二作者)

[16] Xu, S.; Shao, Y.; et al. Preparation, Characterization and Reactivity of Trifluoromethoxy Palladium(II) Complexes. New J. Chem. 202246, 20760. (第二作者)

[17] Zhang, D.; Shao, Y.; et al. Mechanistic Study on the Bidentate Nitrogen-Ligated Iodine(V) Reagent Promoted Oxidative Dearomatization of Phenols. Acta Chimica Sinica 202179, 1394. (第二作者)

[18] Cai, S.; Tang, H.; Li, B.; Shao, Y.; et al. Formaldehyde-Mediated Hydride Liberation of Alkylamines for Intermolecular Reactions in Hexafluoroisopropanol. J. Am. Chem. Soc. 2024146, 5952. (第四作者)

[19] Zhao, Q.; Li, Y.; Ren, Z.; Shao, Y.; et al. Catalytic Asymmetric Reactions of Ketimines and Alkenes via [2+2] Cycloaddition: Chemical Reactivity Controlled by Switching a Heteroatom. J. Am. Chem. Soc. 2024146, 32088. (第四作者)