121. Controlling pyramidal nitrogen chirality by asymmetric organocatalysis (Xie, 2025)

120. Merging of Light/Dark Palladium Catalytic Cycles Enables Multicomponent Tandem Alkyl Heck/Tsuji−Trost Homologative Amination Reaction toward Allylic Amines (Ye, 2025)

119. Deaminative cross-coupling of amines by boryl radical β-scission (Zhou, 2025)

118. Alcohols as alkylating agents in heteroarene C–H functionalization (Chen,2025)

117. Photocatalyst-Regulated Trifluoromethoxylation of Aryl Halides under Silver Promotion (Luo, 2025)

116. Remote-Markovnikov Hydrobromination and Hydrochlorination of Allyl Carboxylates via Dual Photoredox/Cobalt Catalysis (Xie, 2025)

115. A General Copper-Catalyzed Radical Cross-Coupling of Unactivated Alkyl Halides (Ying, 2025)

114. Photoinduced Copper-Catalyzed Enantioselective Alkylalkynylation of Alkenes via Polarity-Matched Hydrogen Atom Transfer (Ye, 2025)

113. Intermolecular Anti-Markovnikov Hydroamination of Unactivated Alkenes with Sulfonamides Enabled by Proton-Coupled Electron Transfer (Chen, 2025）

112. Bridging the pyridine-pyridazine synthesis gap by skeletal editing (Xie, 2025)

111. Spin Delocalization of Nitrile-Ligated Diarylboryl Radicals Enables Photochemical Boracycle (Zhou, 2025)

110. Hydrogen-Bonding-Driven Site-Selective Activation of α-C(sp3)─H in Alcohols （Ying, 2025)

109. Enantioselective Three-Component α-Allylic Alkylation of α-Amino Esters by Synergistic Photoinduced Pd/Carbonyl Catalysis (Luo, 2025)

108. Photoinduced Copper-Catalyzed Enantioselective Alkylalkynylation of Alkenes via Polarity-Matched Hydrogen Atom Transfer (Zhou, 2025)

107. Phosphonium Ylide as Hydrogen Atom Transfer Catalyst Platform Based on Carbon-Centered Radical with High Structural Tunability (Ying, 2025)

106. A General Platform for Visible Light Sulfonylation Reactions Enabled by Catalytic Triarylamine EDA Complexes (Luo, 2025)

105. Generalizing arene C–H alkylations by radical–radical cross-coupling （Zhou, 2025)

104. Stereodivergent Construction of Enamides via a Radical-Mediated Isodesmic Reaction (Ying, 2025)

103. N‑Protonated Acridinium Catalyst Enables Anti-Markovnikov Hydration of Unconjugated Tri- and Disubstituted Olefins (Luo, 2025)

102. Photoredox-Catalyzed Nucleophilic Aromatic Substitution of Halophenols with Azoles via Oligomeric Phenylene Oxide Radicals (Zhang, 2025)

101. Difunctionalization of bicyclo[1.1.0]butanes enabled by merging C−C cleavage and ruthenium-catalysed remote C−H activation (Chen, 2025)

100. Halogen-atom and group transfer reactivity enabled by hydrogen tunneling (Zhou, 2025)

99. Radical Addition to Strained σ‑Bonds Enables the Stereocontrolled Synthesis of Cyclobutyl Boronic Esters (Ying, 2025)

98. Copper-Catalyzed Selective Amino-alkoxycarbonylation of Unactivated Alkenes with CO (Zhang, 2025)

97. Aminoalkylation of Alkenes Enabled by Triple Radical Sorting (Xie, 2025)

96. Sequential Photocatalysis for Homologative Diversification of α‑Amino Acids to β‑Amino Acids Via Phosphonium Ylide Linchpin Strategy (Luo, 2025)

95. β-C−H bond functionalization of ketones and esters by cationic Pd complexes (Chen, 2025)

94. Iterative One-Carbon Homologation of Unmodified Carboxylic Acids (Luo, 2024)

93. Stereoselective Radical Acylfluoroalkylation of Bicyclobutanes via NHeterocyclic Carbene Catalysis (Ying, 2024）

92. Intermolecular Asymmetric Arylative Dearomatization of 1‑Naphthols (Chen, 2024）

91. Visible-Light-Driven Carboxylative 1,2-Difunctionalization of C-C Bonds with Tetrabutylammonium Oxalate. (Luo, 2024)

90. Homologation of Carboxylic Acids Using a Radical-Polar Conjunctive Reagent. (Zhang, 2024)

89. Double alkyl–alkyl bond construction across alkenes enabled by nickel electron-shuttle catalysis. (Luo, 2024)

88. Visible-Light-Mediated Deaminative Three-Component Dicarbofunctionalization of Styrenes with Benzylic Radicals. (Ying, 2024)

87. Ni-Catalyzed Enantioselective Reductive Cyclization/Amidation and Amination of 1,6-Enynes and 1,7-Enynes. (Chen, 2024)

86. Cooperative Phosphine-Photoredox Catalysis Enables N−H Activation of Azoles for Intermolecular Olefin Hydroamination (Luo, 2024)

85. Radical Polarity (Ying, 2024)

84. Photochemical phosphorus-enabled scaffold remodeling of carboxylic acids (Zhang, 2024)

83. Radical Replacement Process for Ligated Boryl Radical-Mediated Activation of Unactivated Alkyl Chlorides for C(sp3)−C(sp3) Bond Formation (Zhou, 2024)

82. Regiodivergent Functionalization of Protected and Unprotected Carbohydrates using Photoactive 4-Tetrafluoropyridinylthio Fragment as an Adaptive Activating Group (Luo, 2024)

81. Visible-Light-Mediated Energy Transfer Enables the Synthesis of β-Lactams via Intramolecular Hydrogen Atom Transfer (Ying, 2024)

80. Stereoselective Construction of Multifunctional C‑Glycosides Enabled by Nickel-Catalyzed Tandem Borylation/Glycosylation （Chen, 2024)

79. Catalyst Control over S(IV)-stereogenicity via Carbene-derived Sulfinyl Azolium Intermediates （Xie, 2024）

78. Visible-Light-Promoted Enantioselective α‑Amidation of Aldehydes by Harnessing Organo-Iron Dual Catalysis (Zhang, 2024)

77. A radical approach for the selective C–H borylation of azines (Zhou, 2024)

76. Ligand-Enabled, Cysteine-Directed β‑C(sp3)−H Arylation of Alanine in Linear and Cyclic Peptides: Overcoming the Inhibitory Effect of Peptide Bonds （Chen, 2024)

75. Modular assembly of arenes, ethylene and heteroarenes for the synthesis of 1,2-arylheteroaryl ethanes (Xie, 2024)

74. General Regio- and Diastereoselective Allylic C−H Oxygenation of Internal Alkenes （Zhang, 2024)

73. Ni/Photoredox-Catalyzed Enantioselective Acylation of α‑Bromobenzoates with Aldehydes: A Formal Approach to Aldehyde-Aldehyde Cross-Coupling (Zhou, 2024)

72. Palladium catalyzed C(sp3)–H bond activation of free carboxylic acids: An adventure of ligand evolution (Chen, 2024)

71. Asymmetric Three-Component Radical Alkene Carboazidation by Direct Activation of Aliphatic C−H Bonds (Xie, 2024)

70. Alkene 1,3-Difluorination via Transient Oxonium Intermediates (Zhang, 2024)

69. Stepwise on-demand functionalization of multihydrosilanes enabled by a hydrogen-atom-transfer photocatalyst based on eosin Y (Zhou, 2024)

68. Copper-catalyzed dehydrogenation or actonization of C(sp3)−H bonds (Chen, 2024)

67. Aminative Suzuki–Miyaura coupling (Zhang, 2024)

66. Photocatalytic α-Tertiary Amine Synthesis via C–H Alkylation of Unmasked Primary Amines (Xu, 2024)

65. Alkene dialkylation by triple radical sorting (2024, Zhou)

64. Site-Selective Electrochemical Arene C−H Amination (Xie, 2024)

63. Three-component dicarbofunctionalization of allylamines via nucleopalladation pathway: unlocking vicinal and geminal selectivity. (Chen, 2024).

62. Alkene dialkylation by triple radical sorting (Zhou, 2024)

61. Rapid and Modular Access to Quaternary Carbons from Tertiary Alcohols via Bimolecular Homolytic Substitution (Xie,  2023)

60. Bicyclopentylation of Alcohols with Thianthrenium Reagents (Zhang, 2023)

59. Photocatalytic Anti-Markovnikov Hydroamination of Alkenes with Primary Heteroaryl Amines (Zhou, 2023)

58. Visible-light photoredox-catalyzed selective carboxylation of C(sp3)-F bonds with CO2 (Zhang, 2023)

57. Photocatalytic Dehydroxymethylative Arylation by Synergistic Cerium and Nickel Catalysis (Xie, 2023)

56. Metal-free photosensitized radical relay 1,4- carboimination across two distinct olefins (Zhang, 2023)

55. Reductive Cross-Coupling of Olefins via a Radical Pathway (Zhou, 2023）

54. Dicarboxylation of alkenes, allenes and (hetero) arenes with CO2 via visible-light photoredox catalysis (Zhang, 2023)

53. Remote C-H Olefination of Heterocyclic Biaryls Enabled by Reversibly Bound Templates (Xie, 2023)

52. Selective sp3 C–H alkylation via polarity-match based cross-coupling (Zhou, 2023)

51. Transannular C–H functionalization of cycloalkane carboxylic acids (Zhang, 2023)

50. Photocatalytic Anti-Markovnikov Hydroamination of Alkenes with Primary Heteroaryl Amines (Xie, 2023)

49. Visible-Light-Driven Alkene Dicarboxylation with Formate and CO2 Under Mild Conditions (Zhang, 2023)

48. Nickel/Photoredox Dual-Catalyzed Regiodivergent Aminoalkylation of Unactivated Alkyl Halides (Zhou, 2023)

47. Oxidative rearrangement of 1,1-disubstituted alkenes to ketones (Zhang, 2023)

46. Understanding Ni(II)-Mediated C(sp3)-H Activation: Tertiary Ureasas Model Substrates. (Chen, 2023).

45. Metal-Free Photochemical Imino-Alkylation of Alkenes with Bifunctional Oxime Esters (Zhou, 2023)

44. Sterically controlled isodesmic late-stage C–H iodination of arenes (Zhang, 2023)

43. Nickel(IV) Intermediates in Aminoquinoline Directed C(sp2)-C(sp3) Coupling. (Chen, 2023).

42. Bidirectional Elongation Strategy Using Ambiphilic Radical Linchpin for Modular Access to 1,4-Dicarbonyls via Sequential Photocatalysis. (Lan, 2023.8.19)

41. Escape from Palladium: Nickel-Catalyzed Catellani Annulation (Zhang, 2023)

40. Oxidative Cross Dehydrogenative Coupling of N‑Heterocycles with Aldehydes through C(sp3)−H Functionalization. (Lan, 2023.9.26)

39. Electron-Deficient Fluoroarene-Mediated Synthesis of Trifluoromethyl Ketones from Carboxylic Acids (Zhang, 2023)

38. Nickel-Catalyzed Regioselective Reductive Ring Opening of Aryl Cyclopropyl Ketones with Alkyl Bromides. (Chen, 2023).

37. Nickel-Catalyzed Reductive Alkyne Hydrocyanation Enabled by Malononitrile and a Formaldehyde Additive. (Lan, 2023.11.11)

36. Regio-controllable [2+2] benzannulation with two adjacent C(sp3)-H bonds. (Chen, 2023).

35. Photoredox-Nickel Dual-Catalyzed C Alkylation of Secondary Nitroalkanes: Access to Sterically Hindered α Tertiary Amines (Zhang, 2023)

34. Atroposelective remote meta-C–H activation. (Lan, 2023.6.24)

33. Visible-light photoredox-catalyzed selective carboxylation of C(sp3) F bonds with CO2 (Zhang, 2023)

32. Transannular C-H functionalization of cycloalkane carboxylic acids. (Chen, 2023)

31. Photoinduced Five-Component Radical Relay Aminocarbonylation of Alkenes (Xu, 2023)

30. Cu-Mediated Thianthrenation and Phenoxathiination of Arylborons. (Lan, 2023.5.20)

29. Visible-light-driven three-component reductive 1,2-diarylation of alkenes (Xu, 2023)

28. Hydrogen-bond-acceptor ligands enable distal C(sp3)-H arylation of free alcohols. (Chen, 2023).

27. Nickel-Catalyzed C Alkylation of Nitroalkanes with Unactivated Alkyl Iodides (Zhang, 2023)

26. Visible light-driven conjunctive olefination (Xu, 2023)

25. Amide-Directed, Rhodium-Catalyzed Regio- and Enantioselective Hydroacylation of Internal Alkenes with Unfunctionalized Aldehydes. (Chen, 2023).

24. Pd(II)-Catalyzed Hydroxyl-Directed C-H Activation/C-O Cyclization: Expedient Construction of Dihydrobenzofurans. (Lan, 2022.11.26)

23. MPAI-Ligand Accelerated Pd-Catalyzed C(sp3)-H Arylation of Free Aliphatic Acids. (Chen, 2022).

22. Pd(0)/Blue Light Promoted Carboiodination Reaction − Evidence for Reversible C−I Bond Formation via a Radical Pathway. (Lan, 2022.11.19)

21. C(sp3)–C(sp3) coupling of non-activated alkyl iodides with electron-deficient alkenes via visible light/silane-mediated alkyl-radical formation (Xu, 2022)

20. PdII-Catalyzed γ‑C(sp3)−H (Hetero) arylation of Ketones Enabled by Transient Directing Groups. (Chen, 2022).

19. Distal Alkenyl C−H Functionalization via the Palladium/Norbornene Cooperative Catalysis (Lan, 2022.11.5)

18. PdII−Catalyzed Site-selective β-and γ‑C(sp3)-H Arylation of Primary Aldehydes Controlled by Transient Directing Groups. (Chen, 2022).

17. Synthetic Methods Driven by the Photoactivity of Electron Donor− Acceptor Complexes (Xu, 2022)

16. Accessing α‑Amino Ketyl Radicals from β‑Amino Alcohols via Chemoselective Hydrogen Atom Transfer Catalysis. (Lan, 2022.10.22)

15. Visible Light Uranyl Photocatalysis: Direct C−H to C−C Bond Conversion (Xu, 2022)

14. Highly Efficient Synthesis of Alkylboronate Esters via Cu(II)-Catalyzed Borylation of Unactivated Alkyl Bromides and Chlorides in Air. (Lan, 2022.7.9)

13. Cobalt-Catalyzed Cross-Coupling Reactions of Arylboronic Esters and Aryl Halides (Xu, 2022)

12. Synthesis and Glycosidation of Anomeric Halides. (Lan, 2022.6.25)

11. Cross-Coupling Hydrogen Evolution by Visible Light Photocatalysis Toward C(sp2)−P Formation: Metal-Free C−H    Functionalization of Thiazole Derivatives with Diarylphosphine Oxides (Xu, 2022)

10. Merging Photoredox and Nickel Catalysis: The Decarboxylative Cross Coupling of Carboxylic Acids with Vinyl Halides. (Lan, 2022.6.4)

9. Photoinduced Site-Selective C-H Functionalization by Pyridine N-oxide Based HAT Catalysts (Xu, 2022)

8. Regioselective Transition-Metal-Free Allyl–Allyl Cross-Couplings. (Lan, 2022.5.28)

7. C(sp3)–H functionalizations of light hydrocarbons using decatungstate photocatalysis in flow (Xu, 2022)

6. Synthesis of Substituted Oxazoles by Visible-Light Photocatalysis. (Lan, 2022.2.26)

5. Asymmetric Total Synthesis of (+)-Waihoensene. (Lan, 2021.12.03)

4. Rhodium-catalyzed intermolecular enantioselective Alder–ene type reaction of cyclopentenes with silylacetylenes (Xu, 2021)

3. Catalytic Asymmetric Csp3-H Functionalization under Photoredox Conditions by Radical Translocation and Stereocontrolled Alkene Addition. (Lan, 2021.12.17）

2. Remote site-selective C–H activation directed by a catalytic bifunctional template. (Lan, 2021.12.24)

1. Divergent Aminocarbonylations of Alkynes Enabled by Photoredox/Nickel Dual Catalysis (Xu, 2021)