程中桦、何颜Chichibabin偶联制备共轭微孔高分子用于光催化工作被《Polymer Chemistry》接收。该工作与中科大徐航勋教授合作,采用醛酮缩合快速制备吡啶基共轭微孔高分子,避免昂贵金属催化剂,产物成功用于可见光催化产氢、产氧。
Research work of 'Rapid metal-free synthesis of pyridyl-functionalized conjugated microporous polymers for visible-light-driven water splitting' published in Polymer Chemistry.
Abstract:
A rapid metal-free synthetic approach was applied to synthesize pyridyl-functionalized conjugated microporous polymers (PCMPs) via an aminative cyclization between aryl aldehydes and ketones without any metal catalysts. PCMPs exhibited suitable electronic structures for visible-light-driven water splitting, offering numerous opportunities in developing new polymer photocatalysts for future solar-to-chemical conversion.
https://pubs.rsc.org/en/content/articlelanding/2020/py/d0py00249f/unauth#!divAbstract