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当前位置: 首页   >  课题组新闻   >  程中桦、何颜Chichibabin偶联制备共轭微孔高分子用于光催化工作被《Polymer Chemistry》接收 Research work of 'Rapid metal-free synthesis of pyridyl-functionalized conjugated microporous polymers for visible-light-driven water splitting' published in <Polymer Chemistry>
程中桦、何颜Chichibabin偶联制备共轭微孔高分子用于光催化工作被《Polymer Chemistry》接收 Research work of 'Rapid metal-free synthesis of pyridyl-functionalized conjugated microporous polymers for visible-light-driven water splitting' published in <Polymer Chemistry>
发布时间:2020-04-14

程中桦、何颜Chichibabin偶联制备共轭微孔高分子用于光催化工作被《Polymer Chemistry》接收。该工作与中科大徐航勋教授合作,采用醛酮缩合快速制备吡啶基共轭微孔高分子,避免昂贵金属催化剂,产物成功用于可见光催化产氢、产氧。


Research work of 'Rapid metal-free synthesis of pyridyl-functionalized conjugated microporous polymers for visible-light-driven water splitting' published in Polymer Chemistry.


Abstract: 

A rapid metal-free synthetic approach was applied to synthesize pyridyl-functionalized conjugated microporous polymers (PCMPs) via an aminative cyclization between aryl aldehydes and ketones without any metal catalysts. PCMPs exhibited suitable electronic structures for visible-light-driven water splitting, offering numerous opportunities in developing new polymer photocatalysts for future solar-to-chemical conversion.

Graphical abstract: Rapid metal-free synthesis of pyridyl-functionalized conjugated microporous polymers for visible-light-driven water splitting

https://pubs.rsc.org/en/content/articlelanding/2020/py/d0py00249f/unauth#!divAbstract