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祝贺焦嘉晨同学 Chemical Communications 论文发表
发布时间:2023-02-11

Hydroxyl Radical-dominated Selective Oxidation of Ethylbenzene over a Photoactive Polyoxometalate-based Metal-organic Framework

Jiachen Jiao, Ting Zhang, Jinagbo Xu, Kaixin Guo, Jie Li, Qiuxia Han*

                                              

A new 3D photoactive CuW-TPT with high accessible empty space was assembled, which displays high efficient hole-electron separation and ordered electron transfer under irradiation due to the continuous coordination bonds and the π−π stacking interactions. It exhibits an excellent yield and selectivity for oxidation of ethylbenzene with O2/H2O as green oxidants under mild conditions by finely control of generation of ROS.