Tian-Zhen Li, Cheng-Cheng Tian, Wei Chen, Zi-Yun Zou, Jia-Liang Yang, Fang-Xi Liu, Xinyao Li,* Hong-Hao Zhang,* and Feng Shi*, Photoredox/Nickel-Cocatalyzed Asymmetric C–O and C–S Coupling for Atroposelective Synthesis of N-Heterobiaryls, Angew. Chem. Int. Ed. 2025, e202516584. DOI:10.1002/anie.202516584