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祝贺王吉鑫,段志丽,刘星辰,董守诚和陈开鑫的研究论文被 Angew. Chem., Int. Ed.接收发表
发布时间:2022-02-18


A new type of salt-stabilized solid silylzinc pivalates prepared from the silyllithium reagents via transmetalation with Zn(OPiv)2 is reported. These silylzinc pivalates showed enhanced air and moisture stability and unique reactivity in the nickel-catalyzed regioselective alkyl and benzylsilylation of alkenes. Kinetic experiments highlighted the crucial involvement of OPiv-coordination in improving the reactivity of silylzinc pivalates.