导师简介
中国科学院上海有机化学研究所氟化学重点实验室研究员、课题组长、博士生导师。2012年在中国科学院上海有机化学研究所获有机化学博士学位,师从胡金波研究员。2013年3月-2017年2月在美国麻省理工学院化学系Timothy
M. Swager课题组进行博士后研究。期间到伊利诺伊香槟分校Jeffrey S.Moore小组交流访问。近五年,以第一作者在J. Am. Chem. Soc.和Angew. Chem., Int. Ed. 两期刊发表论文8篇。
代表性论文:
1.
Zhao, Y.; Rocha, S. V.; Swager, T. M. Mechanochemical Synthesis of
Extended Iptycenes. J. Am. Chem. Soc. 2016, 138, 13834-13837.
2.
Zhao, Y.; Chen, L.; Swager, T. M. Simultaneous Identification of Neutral
and Anionic Species in Complex Mixtures without Separation. Angew.
Chem., Int. Ed. 2016, 55, 917-921.
3. Zhao, Y.;
Jiang, F.; Hu, J. Spontaneous Resolution of Julia-Kocienski
Intermediates Facilitates Phase Separation to Produce Z- and
E-Monofluoroalkenes. J. Am. Chem. Soc. 2015, 137. 5199-5203. Highlighted in JACS Spotlights and Chem-Station
4.
Zhao, Y.; Swager, T. M. Simultaneous Chirality Sensing of Multiple
Amines by 19F NMR. J. Am. Chem. Soc. 2015, 137, 3221-3224. Highlighted
in C&E News, JACS Spotlights, Chemistry Views, and Chem-Station
5.
Zhao, Y.; Markopoulos, G.; Swager, T. M. 19F NMR Fingerprints:
Identification of Neutral Organic Compounds in a Molecular Container. J.
Am. Chem. Soc. 2014, 136, 10683-10690. Highlighted in “In the Pipeline”
6. Zhao, Y.;
Swager, T. M. Detection and Differentiation of Neutral Organic Compound
by 19F NMR with a Tungsten Calix[4]arene Imido Complex. J. Am. Chem. Soc. 2013, 135, 18770-18773.
7. Zhao, Y.;
Ni, C.; Jiang, F.; Gao, B.; Shen, X.; Hu, J. Copper-Catalyzed
Debenzoylative Monofluoromethylation of Aryl Iodides Assisted by the
Removable (2-Pyridyl)sulfonyl Group. ACS Catal. 2013, 3, 631-634.
8. Zhao, Y.;
Gao, B.; Ni, C.; Hu, J. Copper-Mediated Fluoroalkylation of Aryl
Iodides Enables Facile Access to Diverse Fluorinated Compounds: The
Important Role of the (2-Pyridyl)sulfonyl Group. Org. Lett. 2012, 14, 6080-6083. Highlighted in Synfacts
9. Zhao, Y.;
Bing, G.; Hu, J. From Olefination to Alkylation: In-Situ Halogenation
of Julia-Kocienski Intermediates Leading to Formal Nucleophilic Iodo-
and bromodifluoromethylation of Carbonyl Compounds. J. Am. Chem. Soc. 2012, 134, 5790-5793.
10.
Zhao, Y.; Hu, J., Palladium-Catalyzed 2,2,2-Trifluoroethylation of
Organoboronic Acids and Esters. Angew. Chem., Int. Ed. 2012, 51,
1033-1036.
11. Zhao, Y.;
Huang, W.; Zheng, J.; Hu, J., Efficient and Direct Nucleophilic
Difluoromethylation of Carbonyl Compounds and Imines with Me3SiCF2H at
Ambient or Low Temperature. Org. Lett. 2011, 13, 5342-5345. Highlighted
in Synfacts Me3SiCF2H is now commercially available at Sigma-Aldrich
12.
Zhao, Y.;
Huang, W.; Zhu, L.; Hu, J., Difluoromethyl 2-Pyridyl Sulfone: A New
gem-Difluoroolefination Reagent for Aldehydes and Ketones. Org. Lett.
2010, 12, 1444-1447. Difluoromethyl 2-Pyridyl Sulfone is now
commercially available at Sigma-Aldrich
有意应聘者请将个人简历、研究小结和代表性论文发至zhaoyanchuan@sioc.ac.cn。欢迎加盟!