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康彦彪 研究员 收藏
中国科学技术大学     化学与材料科学学院
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个人简介

2012.4-至今 中国科学技术大学化学系 特任研究员 2010.4-2012.3 德国海德堡大学催化实验室(BASF支持) 博士后 2008.8-2010.3 德国海德堡大学 洪堡学者 2007.8-2008.7 美国Brandeis大学 博士后 2002.9-2007.7 中国科学院上海有机化学研究所 博士 1998.9-2002.7 南京大学化学化工学院 学士 获奖及荣誉 (1) 洪堡奖学金,亚历山大.冯.洪堡基金会,2007。 (2) 国家自然科学奖(二等奖),2012(排名第五)。 (3) 张宗植青年教师奖 (2016)。

研究领域

1. 基于机理研究的有机新反应探索。 2. 基于化学反应动力学的有机反应机理研究。 3. 不对称催化和合成。

近期论文

Liu, J.; Zheng, H.-X.; Yao, C.-Z.; Sun, B.-F.; Kang, Y.-B.* Pharmaceutical-Oriented Selective Synthesis of Mononitriles and Dinitriles Directly from Methyl(hetero)arenes: Access to Chiral Nitriles and Citalopram J. Am. Chem. Soc. 2016, 138, 3294−3297。 Chen, X.-M.; Ning, X.-S.; Kang, Y.-B.* Aerobic Acetoxyhydroxylation of Alkenes Co-catalyzed by Organic Nitrite and Palladium Org. Lett. 2016, 18, 5368-5371. Ning, X.-S; Wang, M.-M.; Yao, C.-Z.; Chen, X.-M.; Kang, Y.-B.* Tert-Butyl Nitrite: Organic Redox Cocatalyst for Aerobic Aldehyde-Selective Wacker–Tsuji Oxidation Org. Lett. 2016, 18, 2700-2703. Ge, J.-J.; Yao, C.-Z.; Wang, M.-M.; Zheng, H.-X.; Kang, Y.-B.*; Li, Y.-D. Transition-Metal-Free Deacylative Cleavage of Unstrained C(sp(3))-C(sp(2)) Bonds: Cyanide-Free Access to Aryl and Aliphatic Nitriles from Ketones and Aldehydes Org. Lett. 2016, 18, 228. Xiao, Z.-F.; Ding, T.-H.; Mao, S.-W.; Shah, Z.; Ning, X.-S.; Kang, Y.-B.* Iridium-Catalyzed Cyclization of Isoxazolines and Alkenes: Divergent Access to Pyrrolidines, Pyrroles, and Carbazoles Org. Lett. 2016, 18, ASAP, DOI: 10.1021/acs.orglett.6b02905. Kang, Y.-B.*; Chen, X.-M.; Yao, C.-Z.; Ning, X.-S. Direct oxidative lactonization of alkenoic acids mediated solely by NaIO4: beyond a simple oxidant Chem. Commun. 2016, 52, 6193–6196. Xiao, Z.-F.; Ding, T.-H.; Mao, S.-W.; Ning, X.-S.; Kang, Y.-B.* Zinc Iodide-Mediated Direct Synthesis of 2,3-Dihydroisoxazoles from Alkynes and Nitrones Adv. Synth. Catal. 2016, 358, 1859–1863. Zhang, X.-W.; Xiao, Z.-F.; Zhuang, Y.-J.; Wang, M.-M.; Kang, Y.-B.* Metal-Free Autoxidative Nitrooxylation of Alkenyl Oximes with Molecular Oxygen Adv. Synth. Catal. 2016, 358, 1942–1945. Zhang, X.-W.; Xiao, Z.-F.; Wang, M.-M.; Zhuang, Y.-J.; Kang, Y.-B.* Transition-metal-free oxychlorination of alkenyl oximes: in situ generated radicals with tert-butyl nitrite Org. Biomol. Chem. 2016, 14, 7275–7281. Li, Q.-Q.; Xiao, Z.-F.; Yao, C.-Z.; Zheng, H.-X.; Kang, Y.-B.* Direct Alkylation of Amines with Alcohols Catalyzed by Base Org. Lett. 2015, 17, 5328. Zheng, H.-X.; Xiao, Z.-F.; Yao, C.-Z.; Li, Q.-Q.; Ning, X.-S.; Kang, Y.-B.*; Tang, Y. Transition-Metal-Free Self-Hydrogen-Transferring Allylic Isomerization Org. Lett. 2015, 17, 6102. Yao, C.-Z.; Li, Q.-Q.; Wang, M.-M.; Ning, X.-S.; Kang, Y.-B.* (E)-Specific direct Julia-olefination of aryl alcohols without extra reducing agents promoted by bases Chem. Commun. 2015, 51, 7729.

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