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Huang, F.; Yan, Z.; Zheng, X.; Cai, Y.; Zhang, H.;* Xia, H.* One-pot Synthesis of High-Strained Metal Vinylidene and Metal Carbyne. Chem. - Eur. J. 2022, DOI: 10.1002/chem.202201229.
Chen, S.; Peng, L.; Liu, Y.; Gao, X.; Zhang, Y.; Tang, C.; Zhai, Z.; Yang, L.; Wu, W.; He, X.; Liu, L. L.; He, F.; Xia, H.* Conjugated polymers based on metalla-aromatic building blocks. Proc. Natl. Acad. Sci. U. S. A. 2022, 119, e2203701119.
Lu, N.;† Deng, Z.;† Gao, J.; Liang, C.; Xia, H.;* Zhang, P.* An osmium-peroxo complex for photoactive therapy of hypoxic tumors. Nat. Commun. 2022, 13, 2245.
Yang, L.;† Zhao, H.;† Xie, Y.; Ouyang, P.; Ruan, Y.; Chen, J.; Weng, W.; He, X.;* Xia, H.* Optically reconfigurable shape memory metallo-polymer mediated by a carbolong complex and radically exchangeable covalent bond. Polym. Chem. 2022, 13, 1844-1851.
Cui, F.-H.;† Hua, Y.;† Lin, Y.-M.;* Fei, J.; Gao, L.-H.; Zhao, X.; Xia, H.* Selective Difunctionalization of Unactivated Aliphatic Alkenes Enabled by a Metal-Metallaaromatic Catalytic System. J. Am. Chem. Soc. 2022, 144, 2301–2310.
Wang, H.; Lin, Y. M.;* Chen, S.; Ruan, Y.; Xia, H.* Metallacycle Expansion and Annulation: Access to Tetrazolo‐Fused Osmacycles by Reaction of Cyclic Osmium Carbyne with Sodium Azide. Chin. J. Chem. 2021, 39, 3435-3442.
Cai, Y.;† Hua, Y.;† Lu, Z.; Lan, Q.; Lin, Z.; Fei, J.; Chen, Z.; Zhang, H.;* Xia, H.* Electrophilic aromatic substitution reactions of compounds with Craig-Mobius aromaticity. Proc. Natl. Acad. Sci. U. S. A. 2021, 118, e2102310118.
Tang, C.; Zhao, Y.; Wu, J.; Chen, Z.; Liu, L. L.; Tan, Y. Z.; Zhu, J.;* Xia, H.* Releasing Antiaromaticity in Metal-Bridgehead Naphthalene. J. Am. Chem. Soc. 2021, 143, 15587–15592.
Li, J.; Lu, Z.; Hua, Y.; Chen, D.;* Xia, H.* Carbolong chemistry: nucleophilic aromatic substitution of a triflate functionalized iridapentalene. Chem. Commun. 2021, 57, 8464-8467.
Tang, C.;† Huang, L.;† Sangtarash, S.;† Noori, M.; Sadeghi, H.;* Xia, H.;* Hong, W.* Reversible Switching between Destructive and Constructive Quantum Interference Using Atomically Precise Chemical Gating of Single-Molecule Junctions. J. Am. Chem. Soc. 2021, 25, 9385–9392.
Liu, L.;† Chen, S.;† Qu, Y.; Gao, X.; Han, L.; Lin, Z.; Yang, L.; Wang, W.; Zheng, N.; Liang, Y.; Tan, Y.;* Xia, H.;* He, F.* Nanographene-Osmapentalyne Complexes as a Cathode Interlayer in Organic Solar Cells Enhance Efficiency over 18%. Adv. Mater. 2021, 33, 2101279.
Lin, J.; Luo, M.; Xia, H. The reactivities of novel rhodium CCC-type pincer complexes. Chin. Sci. Bull. 2021, 66, 3333-3341.
Wang, J.;† Li, J.;† Zhou, Y.;† Yu, C.; Hua, Y.; Yu, Y.; Li, R.; Lin, X.; Chen, R.; Wu, H.; Xia, H.;* Wang, H. L.* Tuning an Electrode Work Function Using Organometallic Complexes in Inverted Perovskite Solar Cells. J. Am. Chem. Soc. 2021, 143, 7759-7768.
Wang, H.; Ruan, Y.; Lin, Y.-M.;* Xia, H.* Direct Amidation of Metallaaromatics: Access to N-functionalized Osmapentalynes via a 1,5-Bromoamidated Intermediate. Chem. Sci. 2021, 12, 6315-6322..
Luo, M.;† Cai, Y.;† Lin, X.; Long, L.; Zhang, H.;* Xia, H.* Synthesis, Characterization and Reactivity of Metalla-chalcogenirenium Compounds. Chin. J. Chem. 2021, 39, 1558-1564.
Li J.; Zhuo Q.; Zhuo K.; Chen D.;* Xia H.* Synthesis and Reactivity Studies of Irida-carbolong Complexes. Acta Chimica Sinica 2021, 79, 71-80.
Chen, D.; Hua, Y.; Xia, H.* Metallaaromatic Chemistry: History and Development. Chem. Rev. 2020, 120, 12994-13086.
Leung, A.; Kang, J.; Cai, Y.; Chang, W.; Liu, K.; Xia, H.; Wang, X.* Competition between Ring-Closing Migratory Insertion Polymerization and Monomer Cyclization. Organometallics 2020, 39, 2991-2997.
Huang, F.; Zheng, X.; Lin, X.; Ding, L.; Zhuo, Q.; Wen, T. B.; Zhang, H.;* Xia, H.* Extension of the Simmons–Smith Reaction to Metal-carbynes: Efficient Synthesis of Metallacyclopropenes with σ-Aromaticity. Chem. Sci. 2020, 11, 10159-10166.
Chen, S.; Liu, L.; Gao, X.; Hua, Y.; Peng, L.; Zhang, Y.; Yang, L.; Tan, Y.; He, F.;* Xia, H.* Addition of Alkynes and Osmium Carbynes towards Functionalized dπ–pπ Conjugated Systems. Nat. Commun. 2020, 11, 4651.