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Chen, S.;† Feng, L.;† Peng, L.; Gao, X.; Zhu, Y.; Yang, L.; Chen, D.; Zhang, K.;* Guo, X.; Huang, F.; Xia, H.* Synthesis and Optoelectronic Applications of dπ-pπ Conjugated Polymers with a Di-metallaaromatic Acceptor. Angew. Chem., Int. Ed. 2023, DOI: 10.1002/anie.202305489.
Lai, X.;† Chen, S.;† Gu, X.; Lai, H.; Wang, Y.; Wang, H.; Qu, J.; Kyaw, A. K. K.; Xia, H.;* He, F.* Phenanthroline-Carbolong Interface Suppress Chemical Interactions with Active Layer Enabling Long-Time Stable Organic Solar Cells. Nat. Commun. 2023, 14, 3571.
Chu, Z.; Li, J.; Chen, D.; Lu, Z.; Meng, W.; Luo, M.;* Xia, H.* Formal [2+1] Cycloadditions of a Metallacyclopentadiene Unit with Alkynes: Constructing Tetracyclic Conjugated Frameworks with Bridgehead Metals. Chin. J. Chem. 2023, 41, 1987-1993.
Li, Q.; Fei, J.; Ruan, K.; Hua, Y.; Chen, D.; Luo, M.;* Xia, H.* Reshaping aromatic frameworks: expansion of aromatic system drives metallabenzenoids to metallapentalenes. Chem. Sci. 2023, 14, 5672–5680.
Tang, C.;† Jiang, X.-L.;† Chen, S.; Hong, W.;* Li, J.;* Xia, H.* Stereoelectronic Modulation of a Single-Molecule Junction through a Tunable Metal-Carbon dπ‐pπ Hyperconjugation. J. Am. Chem. Soc. 2023, 145, 10404-10410.
Chu, Z.; Li, J.; Hua, Y.; Luo, M.; Chen, D.;* Xia, H.* Hetero-carbolong chemistry: experimental and theoretical studies of diaza-metallapentalenes. Chem. Commun. 2023, 59, 4173-4176.
Li, Q.; Hua, Y.; Tang, C.; Chen, D.; Luo, M.; Xia, H.* Isolation, Reactivity, and Tunable Properties of a Strained Antiaromatic Osmacycle. J. Am. Chem. Soc. 2023, 145, 7580-7591.
Luo, M.; Chen, D.; Li, Q.; Xia, H.* Unique Properties and Emerging Applications of Carbolong Metallaaromatics. Acc. Chem. Res. 2023, 56, 924-937.
Chen, S.;† Cao, C.;† Yu, Z.; Zhang, A.; Lai, X.; Peng, L.; Hua, Y.; Yang, L.; Jiang, W.; Chen, D.; Wang, Z.;* He, F.;* Xia, H.* A dπ‐pπ Conjugated System with High Mobility and Strong Emission Simultaneously. Adv. Funct. Mater. 2023, 33, 202300359.
Chen, L.;† Lin, L.;† Nath, A. R.;† Zhu, Q.;† Chen, Z.; Wu, J.; Wang, H.; Li, Q.; Lin, W.-F.; Zhu, J.;* Xia, H.* Synthesis and characterization of Craig-type antiaromatic species with [4n+2] π electrons. Proc. Natl. Acad. Sci. U. S. A. 2023, 120, e2215900120.
Lin, Z.;† Cai, Y.;† Zhang, Y.; Zhang, H.;* Xia, H.* Heterocyclic Suzuki–Miyaura coupling reaction of metalla-aromatics and mechanistic analysis of site selectivity. Chem. Sci. 2023,14, 1227-1233.
Zhuo, K.;† Liu, Y.;† Ruan, K.; Hua, Y.; Lin, Y.-M.;* Xia, H.* Ring contraction of metallacyclobutadiene to metallacyclopropene driven by π- and σ-aromaticity relay. Nat. Synth. 2023, 28, e202201229.
Li, J.;† Wang, J.;† Zhou, Y.;† Yu, C.; Liu, H.; Qi, X.; Li, R.; Hua, Y.; Yu, Y.; Chen, R.; Chen, D.; Mao, L.; Xia, H.;* Wang, H.-L.* Boosting the performance and stability of inverted perovskite solar cells by using a carbolong derivative to modulate the cathode interface. Mater. Chem. Front. 2022, 6, 2211-2218.
Li, J.; Chu, Z.; Lu, Z.; Luo, M.; Chen, D.;* Xia, H.* Reactivity Studies of a Hydroxy-Substituted Irida-carbolong Complex. Organometallics 2022, 41, 2589-2596.
Xu, B.;† Mao, W.;† Wu, C.; Li, J.; Lu, Z.; Luo, M.; Liu, L. L.; Mao, L.; Chen, D.;* Xia, H.* A One‐Pot Strategy for the Synthesis of β‐Substituted Rhoda‐ and Irida‐Carbolong Complexes. Chin. J. Chem. 2022, 40, 1777-1784.(Xu and Mao contributed equally to this work.)
Wang, M.;† He, W.;† Hua, Y.;† Xie, X.;† Chen, S.; Zhou, L.; Zhang, Y.; Hou, Y.; Lin, S.; Xia, H.;* Zheng, J.; Hou, X.* Alternative photothermal/electrothermal hierarchical membrane for hypersaline water treatment. SusMat 2022, 2, 679-688.
Cui, F.-H.; Li, Q.; Gao, L.-H.; Ruan, K.; Ma, K.; Chen, S.; Lu, Z.; Fei, J.; Lin, Y.-M.;* Xia, H.* Condensed Osmaquinolines with NIR-II Absorption Synthesized by Aryl C-H Annulation and Aromatization. Angew. Chem., Int. Ed. 2022,134, e202211734.
Liu, H.; Lu, Z.; Zhang, W.; Wang, J.; Lu, Z.; Dai, Q.; Qi, X.; Shi, Y.; Hua, Y.; Chen, R.; Shi, T.;* Xia, H.;* Wang, H. L.* Anchoring Vertical Dipole to Enable Efficient Charge Extraction for High‐Performance Perovskite Solar Cells. Adv. Sci. 2022, 2203640.
Huang, F.; Yan, Z.; Zheng, X.; Cai, Y.; Zhang, H.;* Xia, H.* One-pot Synthesis of High-Strained Metal Vinylidene and Metal Carbyne. Chem. - Eur. J. 2022, 28, e202201229.
Chen, S.; Peng, L.; Liu, Y.; Gao, X.; Zhang, Y.; Tang, C.; Zhai, Z.; Yang, L.; Wu, W.; He, X.; Liu, L. L.; He, F.; Xia, H.* Conjugated polymers based on metalla-aromatic building blocks. Proc. Natl. Acad. Sci. U. S. A. 2022, 119, e2203701119.
Lu, N.;† Deng, Z.;† Gao, J.; Liang, C.; Xia, H.;* Zhang, P.* An osmium-peroxo complex for photoactive therapy of hypoxic tumors. Nat. Commun. 2022, 13, 2245.
Yang, L.;† Zhao, H.;† Xie, Y.; Ouyang, P.; Ruan, Y.; Chen, J.; Weng, W.; He, X.;* Xia, H.* Optically reconfigurable shape memory metallo-polymer mediated by a carbolong complex and radically exchangeable covalent bond. Polym. Chem. 2022, 13, 1844-1851.
Cui, F.-H.;† Hua, Y.;† Lin, Y.-M.;* Fei, J.; Gao, L.-H.; Zhao, X.; Xia, H.* Selective Difunctionalization of Unactivated Aliphatic Alkenes Enabled by a Metal-Metallaaromatic Catalytic System. J. Am. Chem. Soc. 2022, 144, 2301–2310.
Wang, H.; Lin, Y. M.;* Chen, S.; Ruan, Y.; Xia, H.* Metallacycle Expansion and Annulation: Access to Tetrazolo‐Fused Osmacycles by Reaction of Cyclic Osmium Carbyne with Sodium Azide. Chin. J. Chem. 2021, 39, 3435-3442.
Cai, Y.;† Hua, Y.;† Lu, Z.; Lan, Q.; Lin, Z.; Fei, J.; Chen, Z.; Zhang, H.;* Xia, H.* Electrophilic aromatic substitution reactions of compounds with Craig-Mobius aromaticity. Proc. Natl. Acad. Sci. U. S. A. 2021, 118, e2102310118.
Tang, C.; Zhao, Y.; Wu, J.; Chen, Z.; Liu, L. L.; Tan, Y. Z.; Zhu, J.;* Xia, H.* Releasing Antiaromaticity in Metal-Bridgehead Naphthalene. J. Am. Chem. Soc. 2021, 143, 15587–15592.
Li, J.; Lu, Z.; Hua, Y.; Chen, D.;* Xia, H.* Carbolong chemistry: nucleophilic aromatic substitution of a triflate functionalized iridapentalene. Chem. Commun. 2021, 57, 8464-8467.
Tang, C.;† Huang, L.;† Sangtarash, S.;† Noori, M.; Sadeghi, H.;* Xia, H.;* Hong, W.* Reversible Switching between Destructive and Constructive Quantum Interference Using Atomically Precise Chemical Gating of Single-Molecule Junctions. J. Am. Chem. Soc. 2021, 25, 9385–9392.
Liu, L.;† Chen, S.;† Qu, Y.; Gao, X.; Han, L.; Lin, Z.; Yang, L.; Wang, W.; Zheng, N.; Liang, Y.; Tan, Y.;* Xia, H.;* He, F.* Nanographene-Osmapentalyne Complexes as a Cathode Interlayer in Organic Solar Cells Enhance Efficiency over 18%. Adv. Mater. 2021, 33, 2101279.
Lin, J.; Luo, M.; Xia, H. The reactivities of novel rhodium CCC-type pincer complexes. Chin. Sci. Bull. 2021, 66, 3333-3341.
Wang, J.;† Li, J.;† Zhou, Y.;† Yu, C.; Hua, Y.; Yu, Y.; Li, R.; Lin, X.; Chen, R.; Wu, H.; Xia, H.;* Wang, H. L.* Tuning an Electrode Work Function Using Organometallic Complexes in Inverted Perovskite Solar Cells. J. Am. Chem. Soc. 2021, 143, 7759-7768.
Wang, H.; Ruan, Y.; Lin, Y.-M.;* Xia, H.* Direct Amidation of Metallaaromatics: Access to N-functionalized Osmapentalynes via a 1,5-Bromoamidated Intermediate. Chem. Sci. 2021, 12, 6315-6322..
Luo, M.;† Cai, Y.;† Lin, X.; Long, L.; Zhang, H.;* Xia, H.* Synthesis, Characterization and Reactivity of Metalla-chalcogenirenium Compounds. Chin. J. Chem. 2021, 39, 1558-1564.
Li J.; Zhuo Q.; Zhuo K.; Chen D.;* Xia H.* Synthesis and Reactivity Studies of Irida-carbolong Complexes. Acta Chimica Sinica 2021, 79, 71-80.
Chen, D.; Hua, Y.; Xia, H.* Metallaaromatic Chemistry: History and Development. Chem. Rev. 2020, 120, 12994-13086.
Leung, A.; Kang, J.; Cai, Y.; Chang, W.; Liu, K.; Xia, H.; Wang, X.* Competition between Ring-Closing Migratory Insertion Polymerization and Monomer Cyclization. Organometallics 2020, 39, 2991-2997.
Huang, F.; Zheng, X.; Lin, X.; Ding, L.; Zhuo, Q.; Wen, T. B.; Zhang, H.;* Xia, H.* Extension of the Simmons–Smith Reaction to Metal-carbynes: Efficient Synthesis of Metallacyclopropenes with σ-Aromaticity. Chem. Sci. 2020, 11, 10159-10166.
Chen, S.; Liu, L.; Gao, X.; Hua, Y.; Peng, L.; Zhang, Y.; Yang, L.; Tan, Y.; He, F.;* Xia, H.* Addition of Alkynes and Osmium Carbynes towards Functionalized dπ–pπ Conjugated Systems. Nat. Commun. 2020, 11, 4651.
Deng, Z.;† Wu, P.;† Cai, Y.; Sui, Y.; Chen, Z.; Zhang, H.; Wang, B.;* Xia, H.* Dioxygen Activation by Internally Aromatic Metallacycle: Crystallographic Structure and Mechanistic Investigations. iScience 2020, 23, 101379.
Tang, C.; Tang, Y.; Ye, Y.; Yan, Z.; Chen, Z.; Chen, L.; Zhang, L.; Liu, J.; Shi, J.; Xia, H.;* Hong, W.* Identifying the Conformational Isomers of Single-Molecule Cyclohexane at Room Temperature. Chem 2020, 6, 2770-2781.
Lin, J.; Xu, Q.; Lin, X.; Hua, Y.; Chen, D.; Ruan, Y.; Zhang, H.;* Xia, H.* The First OCCCO Pentadentate Chelates: Osmium Mediated Stepwise Oxidations of Terminal Alkynes by Pyridine N‐Oxide. Chin. J. Chem. 2020, 38, 1273-1279.
Luo, M.; Hua, Y.; Zhuo, K.; Long, L.; Lin, X.; Deng, Z.; Lin, Z.; Zhang, H.; Chen, D.; Xia, H.* Carbolong Chemistry: Planar CCCCX-Type (X = N, O, S) Pentadentate Chelates by Formal [3+1] Cycloadditions of Metalla-Azirines with Terminal Alkynes. CCS Chemistry 2020, 2, 758-763.
Luo, M.; Sui, Y.; Lin, X.; Zhu, C.; Yan, Z.; Ruan, Y.; Zhang, H.;* Xia, H.* [3+2] Cycloaddition Reaction of MetallaCyclopropene with Nitrosonium Ion: Isolation of Aromatic Metallaisoxazole. Chem. Commun. 2020, 56, 6806-6809.
Tang, C.; Zheng, J.; Ye, Y.; Liu, J.; Chen, L.; Yan, Z.; Chen, Z.; Chen, L.; Huang, X.; Bai, J.; Chen, Z.; Shi, J.; Xia, H.;* Hong, W.* Electric-Field-Induced Connectivity Switching in Single-Molecule Junctions. iScience 2020, 23, 100770.
Chen, Y.;† Yang, L.;† Zheng, W.; Ouyang, P.; Zhang, H.; Ruan, Y.; Weng, W.;* He, X.;* Xia, H.* Dynamic Polymer Network System Mediated by Radically Exchangeable Covalent Bond and Carbolong Complex. ACS Macro Lett. 2020, 9, 344-349.
Lu, Z.;† Zhu, Q.;† Cai, Y.; Chen, Z.; Zhuo, K.; Zhu, J.; Zhang, H.;* Xia, H.* Access to Tetracyclic Aromatics with Bridgehead Metals via Metalla-click Reactions. Sci. Adv. 2020, 6, eaay2535.
Meng, S.; Zhang, M.; Yao, M.;* Qiu, Z.; Hong, Y.; Lan, W.; Xia, H.; Jin, X. Membrane Fouling and Performance of Flat Ceramic Membranes in the Application of Drinking Water Purification. Water 2019, 11, 2606.
Zhuo, Q.;† Zhang, H.;† Ding, L.; Lin, J.; Zhou, X.; Hua, Y.; Zhu, J.; Xia, H.* Rhodapentalenes: Pincer Complexes with Internal Aromaticity. iScience 2019, 19, 1214-1224.
Luo, M.; Deng, Z.; Ruan, Y.; Cai, Y.; Zhuo, K.; Zhang, H.;* Xia, H. Reactions of Metallacyclopentadiene with Terminal Alkynes: Isolation and Characterization of Metallafulvenallene Complexes. Organometallics 2019, 38, 3053-3059.(ACS Editors’ Choice)
Huang, X.;† Tang, C.;† Li, J.;† Chen, L.-C.;† Zheng, J.; Zhang, P.; Le, J.; Li, R.; Li, X.; Liu, J.;* Yang, Y.; Shi, J.; Chen, Z.; Bai, M.; Zhang, H. L.; Xia, H.; Cheng, J.;* Tian, Z. Q.; Hong, W.* Electric Field-induced Selective Catalysis of Single-Molecule Reaction. Sci. Adv. 2019, 5, eaaw3072.
Tang, C.; Chen, L.; Zhang, L.; Chen, Z.; Li, G.; Yan, Z.; Lin, L.; Liu, J.; Huang, L.; Ye, Y.; Hua, Y.; Shi, J.; Xia, H.;* Hong, W.* Multicenter-Bond-Based Quantum Interference in Charge Transport Through Single-Molecule Carborane Junctions. Angew. Chem., Int. Ed. 2019, 58, 10601-10605.
Chen, Z.;† Chen, L.;† Liu, J.; Li, R.; Tang, C.; Hua, Y.; Chen, L.; Shi, J.; Yang, Y.; Liu, J.; Zheng, J.; Chen, L.; Cao, J.; Chen, H.; Xia, H.;* Hong, W.* Modularized Tuning of Charge Transport through Highly Twisted and Localized Single-Molecule Junctions. J. Phys. Chem. Lett. 2019, 10, 3453-3458.
Wu, F.; Huang, W.; Zhuo, K.; Hua, Y.; Lin, J.; He, G.;* Chen, J.; Nie, L.;* Xia, H.* Carbolong Complexes as Photothermal Materials. Chin. J. Org. Chem. 2019, 39, 1743-1752.
Deng, Z.; Zhu, C.; Hua, Y.; He, G.; Guo, Y.; Lu, R.; Cao, X.; Chen, J.;* Xia, H.* Synthesis and Characterization of Metallapentalenoxazetes from the [2+2] Cycloaddition of Metallapentalynes with Nitrosoarenes. Chem. Commun. 2019, 55, 6237-6240.
Lin, J.; Ding, L.; Zhuo, Q.; Zhang, H.;* Xia, H.* Formal [2+2+2] Cycloaddition Reaction of a Metal–Carbyne Complex with Nitriles: Synthesis of a Metallapyrazine Complex. Organometallics 2019, 25, 5077-5085.
Zhou, X.; Pang, X.; Nie, L.; Zhu, C.; Zhuo, K.; Zhuo, Q.; Chen, Z.; Liu, G.; Zhang, H.;* Lin, Z.; Xia, H. Successive Modification of Polydentate Complexes Gives Access to Planar Carbon- and Nitrogen-based Ligands. Nat. Commun.2019, 10, 1488.
Li, J.; Lin, Y. M.;* Zhang, H.; Chen, Y.; Lin, Z.; Xia, H.* Access to Metal-Bridged Osmathiazine Derivatives by a Formal [4+2] Cyclization. Chem. - Eur. J. 2019, 25, 5077-5085.
Zhang, H.;† Zhao, H.;† Zhuo, K.; Hua, Y.; Chen, J.; He, X.;* Weng, W.;* Xia, H.* "Carbolong" Polymers with Near Infrared Triggered, Spatially Resolved and Rapid Self-Healing Properties. Polym. Chem. 2019, 10, 386-394.(†Zhang and Zhao contributed equally to this work.)
Li, J.; Kang, H.; Zhuo, K.; Zhuo, Q.; Zhang, H.; Lin, Y.-M.;* Xia, H.* Alternation of Metal-Bridged Metallacycle Skeletons: From Ruthenapentalyne to Ruthenapentalene and Ruthenaindene Derivative. Chin. J. Chem. 2018, 36, 1156-1160.
Chen, Z.;† Wang, T.;† Sun, T.; Chen, Z.; Sheng, T.; Hong, Y.-H.; Nan, Z.-A.; Zhu, J.; Zhou, Z.-Y.;* Xia, H.;* Sun, S.-G. Nickel Complexes with Non-innocent Ligands as Highly Active Electrocatalysts for Hydrogen Evolution. Chin. J. Chem. 2018, 36, 1161-1164.
Lu, Z.;† Lin, Q.;† Cai, Y.; Chen, S.; Chen, J.;* Wu, W.; He, X.;* Xia, H.* Cylindrical Nir-Responsive Metallopolymer Containing Möbius Metalla-Aromatics. ACS Macro Lett. 2018, 7, 1034-1038.
Hua, Y.; Lan, Q.; Fei, J.; Tang, C.; Lin, J.; Zha, H.; Chen, S.; Lu, Y.; Chen, J.;* He, X.;* Xia, H. Metallapentalenofuran: Shifting Metallafuran Rings Promoted by Substituent Effects. Chem. - Eur. J. 2018, 24, 14531-14538.
Zhuo, Q.;† Zhang, H.;† Hua, Y.; Kang, H.; Zhou, X.; Lin, X.; Chen, Z.; Lin, J.; Zhuo, K.; Xia, H.* Constraint of a Ruthenium-Carbon Triple Bond to a Five-Membered Ring. Sci. Adv. 2018, 4 (6), eaat0336.
Zhu, C.; Xia, H.* Carbolong Chemistry: A Story of Carbon Chain Ligands and Transition Metals. Acc. Chem. Res. 2018, 51, 1691-1700.
Zhou, X.; Li, Y.; Shao, Y.; Hua, Y.; Zhang, H.; Lin, Y.-M.;* Xia, H.* Reactions of Cyclic Osmacarbyne with Coinage Metal Complexes. Organometallics 2018, 37, 1788-1794.
Lin, Q.;† Li, S.;† Lin, J.;† Chen, M.; Lu, Z.; Tang, C.; Chen, Z.; He, X.; Chen, J.;* Xia, H.* Synthesis and Characterization of Photothermal Osmium Carbolong Complexes. Chem. - Eur. J. 2018, 24, 8375-8381.
Zhou, X.; Huang, F.; Tang, C.; Zhuo, Q.; Chen, Z.; Zhang, H.;* Xia, H. A Missing Member of Conjugated N-Heterocycles: Realizing Pyrido[1,2-α]azepine by Reacting Ruthenium Alkenylcarbene Complex with Alkyne. Chem. Commun. 2018, 54, 4009-4012.
Wang, T.;† Chen, Z.-X.;† Chen, Y.-G.; Yang, L.-J.;* Yang, X.-D.; Ye, J.-Y.; Xia, H.-P.; Zhou, Z.-Y.;* Sun, S.-G. Identifying the Active Site of N-Doped Graphene for Oxygen Reduction by Selective Chemical Modification. ACS Energy Lett. 2018, 3, 986-991.
Wang, T.;† Chen, Z.-X.;† Yu, S.; Sheng, T.; Ma, H.-B.; Chen, L.-N.; Rauf, M.; Xia, H.-P.; Zhou, Z.-Y.;* Sun, S.-G. Constructing Canopy-Shaped Molecular Architectures to Create Local Pt Surface Sites with High Tolerance to H2S and CO for Hydrogen Electrooxidation. Energy Environ. Sci. 2018, 11, 166-171.
Lu, Z.; Cai, Y.; Wei, Y; Lin, Q.; Chen, J.;* He, X.; Li, S.; Wu, W.; Xia, H.* Photothermal Möbius Aromatic Metallapentalenofuran and Its NIR-Responsive Copolymer. Polym. Chem. 2018, 9, 2092-2100.
Chen, J.;* Lin, Q.; Li, S.; Lu, Z; Lin, J.; Chen, Z.; Xia, H.* Synthesis and Characterization of an Osmapentalene Derivative Containing a β-Agostic Os···H–C(sp3) Interaction. Organometallics 2018, 37, 618-623.
Zhu, C.; Zhu, J.; Zhou, X.; Zhu, Q.; Yang, Y.; Wen, T. B.; Xia, H.* Isolation of an Eleven‐Atom Polydentate Carbon‐Chain Chelate Obtained by Cycloaddition of a Cyclic Osmium Carbyne with an Alkyne. Angew. Chem., Int. Ed. 2018, 57, 3154-3157.
Zhou, X.; Zhang, H.* Reactions of Metal-Carbon Bonds within Six-Membered Metallaaromatic Rings. Chem. - Eur. J. 2018, 24, 8962-8973.
Hua, Y.; Zhang, H.;* Xia, H.* Aromaticity: History and Development. Chin. J. Org. Chem. 2018, 38, 11-28.
Wang, H.;† Zhou, X.;† Xia, H.* Metallaaromatics Containing Main‐Group Heteroatoms. Chin. J. Chem. 2018, 36, 93-105.
Zhou, X.; Wu, J.; Hao, Y.; Zhu, C.; Zhuo, Q.; Xia, H.;* Zhu, J.* Rational Design and Synthesis of Unsaturated Se-Containing Osmacycles with σ-Aromaticity. Chem. - Eur. J. 2018, 24, 2389-2395.
Yang, C.;† Lin, G.;† Zhu, C.;† Pang, X.; Zhang, Y.; Wang, X.; Li, X.; Wang, B.;* Xia, H.;* Liu, G.* Metalla-Aromatic Loaded Magnetic Nanoparticles for MRI/Photoacoustic Imaging-Guided Cancer Phototherapy. J. Mater. Chem. B 2018, 6, 2528-2535.
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