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冯小明 教授, 博导 收藏
四川大学     化学学院
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个人简介

1981-1988 兰州大学化学系有机化学专业学习,分获理学学士学位和理学硕士学位。 1993-1996 中国科学院化学研究所学习,获理学博士学位。 1988-1993 西南师范大学化学系从事有机化学教学和科研工作,历任助教和副教授。 1996-2000 中国科学院成都有机化学研究所从事不对称催化反应研究,历任副研究员和研究员,不对称合成联合开放实验室副主任,于1999被评聘为博士生导师。 1998-1999 美国Colorado State University化学系做博士后研究。 2000- 四川大学化学学院教授,博士生导师,四川大学学术委员会委员,四川大学学位委员会委员,中国化学会有机化学学科委员,绿色化学与技术教育部重点实验室副主任。 2001年入选教育部“跨世纪优秀人才培养计划” 2002年获国家杰出青年科学基金资助 2002年四川省科技进步奖壹等奖(第七完成人) 2002年四川省有突出贡献优秀专家称号 2004年入选四川省学术与技术带头人和获国务院政府特殊津贴 2005年入选教育部长江学者特聘教授 2007年获宝钢优秀教师奖 2007年入选人事部“新世纪百千万人才工程”国家级人选 2008年获教育部“长江学者和创新团队发展计划”创新团队资助(学术带头人) 2009年获教育部自然科学一等奖(第一完成人) 2009年获全国优秀教师和四川省模范教师称号 2010年获第六届四川省高等教育教学成果一等奖(第五完成人) 2010年获国家自然科学基金委创新研究群体资助(学术带头人) 2010年获药明康德公司颁发的“生命化学奖”二等奖 2011年获中国化学会有机化学委员会颁发的“有机合成创造奖” 2011年获全国优秀博士学位论文指导教师荣誉称号 基于“新型手性催化剂和高效高选择性的不对称催化新反应”研究入选“2011年中国高等学校十大科技进展” 研究工作入选中科院2012《科学发展报告》和《国家自然科学基金资助项目优秀成果选编》 2012年获国家自然科学奖二等奖(第一完成人)

研究领域

从事不对称合成方法学及手性医药、农药和具有生理活性化合物的合成研究

近期论文

Jun Li, Lili Lin, Bowen Hu, Pengfei Zhou, Tianyu Huang, Xiaohua Liu* and Xiaoming Feng*, Gold(I)/Chiral N,N’-Dioxide-Nickel(II) Relay Catalysis for Asymmetric Tandem Intermolecular Hydroalkoxylation/Claisen Rearrangement, Angew. Chem. Int. Ed.2017, 56, 885-888 Xiangjin Lian, Lili Lin, Kai Fu, Baiwei Ma, Xiaohua Liu and Xiaoming Feng*, A New Approach on Asymmetric Mannich Reaction Catalyzed by Chiral N,N′-Dioxide–Metal Complexes, Chem. Sci.2017, 8, 1238-1242 Guojin Wang, Yu Tang, Yu Zhang, Xiaohua Liu,* Lili Lin, and Xiaoming Feng*, Enantioselective Synthesis of N-H Free 1,5-Benzothiazepines, Chem. Eur. J. 2017, 23, 554-557. Lili Lin, Xiaoming Feng*, Catalytic Strategies for Diastereodivergent Synthesis, Chem. Eur. J. 2017, 23, 6464-6482. Yong Xia, Lili Lin, Fenzhen Chang, Yuting Liao, Xiaohua Liu,* and Xiaoming Feng*, Asymmetric Ring Opening/Cyclization/Retro-Mannich Reaction of Cyclopropyl Ketones with Aryl 1,2-Diamines for the Synthesis of Benzimidazole Derivatives, Angew. Chem. Int. Ed.2016, 55, 12228–12232. Haipeng Hu, Yangbin Liu, Lili Lin, Yuheng Zhang, Xiaohua Liu,* and Xiaoming Feng*, Kinetic Resolution of 2H-Azirines by Asymmetric Imine Amidation, Angew. Chem. Int. Ed.2016, 55, 10098 –10101. Qian Yao, Yuting Liao, Lili Lin, Xiaobin Lin, Jie Ji, Xiaohua Liu,* and Xiaoming Feng*, Efficient Synthesis of Chiral Trisubstituted 1,2-Allenyl Ketones by Catalytic Asymmetric Conjugate Addition of Malonic Esters to Enynes, Angew. Chem. Int. Ed.2016, 55, 1859 –1863. Yangbin Liu, Xiaohua Liu,* Haipeng Hu, Jing Guo, Yong Xia, Lili Lin, and Xiaoming Feng*, Synergistic Kinetic Resolution and Asymmetric Propargyl Claisen Rearrangement for the Synthesis of Chiral Allenes, Angew. Chem. Int. Ed.2016, 55, 4054 –4058. Quangang Chen, Yu Tang, Tianyu Huang, Xiaohua Liu,* Lili Lin, and Xiaoming Feng; Copper/Guanidine-Catalyzed Asymmetric Alkynylation of Isatins, Angew. Chem. Int. Ed.2016, 55, 5286 –5289. Tengfei Kang, Shulin Ge, Lili Lin, Yan Lu, Xiaohua Liu,* and Xiaoming Feng*, A Chiral N,N′-Dioxide–ZnII Complex Catalyzes the Enantioselective [2+2] Cycloaddition of Alkynones with Cyclic Enol Silyl Ethers, Angew. Chem. Int. Ed.2016, 55, 5541 –5544. Jun Li, Lili Lin, Bowen Hu, Xiangjin Lian, Gang Wang, Xiaohua Liu,* and Xiaoming Feng*, Bimetallic Gold(I)/Chiral N,N′-Dioxide Nickel(II) Asymmetric Relay Catalysis: Chemo- and Enantioselective Synthesis of Spiroketals and Spiroaminals, Angew. Chem. Int. Ed.2016, 55, 6075 –6078. Pengfei Zhou, Yunfei Cai, Xia Zhong, Weiwei Luo, Tengfei Kang, Jun Li, Xiaohua Liu,* Lili Lin, and Xiaoming Feng*, Catalytic Asymmetric Intra- and Intermolecular Haloetherification of Enones: An Efficient Approach to (?)-Centrolobine, ACS Catal.2016, 6, 7778?7783. Fei Tan, Xiaohua Liu,* Xiaoyu Hao, Yu Tang, Lili Lin, and Xiaoming Feng; Asymmetric Catalytic Insertion of α?Diazo Carbonyl Compounds into O?H Bonds of Carboxylic Acids, ACS Catal.2016, 6, 6930?6934. Gang Wang, Xiaohua Liu,*, Yushuang Chen, Jian Yang, Jun Li, Lili Lin, and Xiaoming Feng*, Diastereoselective and Enantioselective Alleno-aldol Reaction of Allenoates with Isatins to Synthesis of Carbinol Allenoates Catalyzed by Gold, ACS Catal.2016, 6, 2482?2486. Yali Xu, Yuting Liao, Lili Lin, Yuhang Zhou, Jun Li, Xiaohua Liu, and Xiaoming Feng*, Catalytic Asymmetric Inverse-Electron Demand 1,3-Dipolar Cycloaddition of Isoquinolinium Methylides with Enecarbamates by a Chiral N,N′-Dioxide/Ag(I) Complex, ACS Catal.2016, 6, 589?592. Jing Guo, Yangbin Liu, Xiangqiang Li, Xiaohua Liu,* Lili Lin and Xiaoming Feng*, Nickel(II)-catalyzed enantioselective cyclopropanation of 3-alkenyl-oxindoles with phenyliodonium ylide via free carbine, Chem. Sci.2016, 7, 2717–2721. Yuting Liao, Xiaohua Liu,* Yu Zhang, Yali Xu, Yong Xia, Lili Lin and Xiaoming Feng*, Asymmetric [3 + 2] cycloaddition of donor–acceptor aziridines with aldehydes via carbon–carbon bond cleavage, Chem. Sci.2016, 7, 3775–3779. Weiwei Luo, Xiao Yuan, Lili Lin, Pengfei Zhou, Xiaohua Liu* and Xiaoming Feng*, A N,N′-dioxide/Mg(OTf)2 complex catalyzed enantioselective a-addition of isocyanides to alkylidene malonates, Chem. Sci.2016, 7, 4736–4740. Jing Guo, Lili Lin, Yangbin Liu, Xiangqiang Li, Xiaohua Liu,* and Xiaoming Feng*, Nickel(II)-Catalyzed Enantioselective α-Vinylation of β-Keto Amides/Esters with Hypervalent Iodine Salts, Org. Lett.2016, 18, 5540?5543. Xiaobin Lin, Sai Ruan, Qian Yao, Chengkai Yin, Lili Lin, Xiaoming Feng, and Xiaohua Liu*; Kinetic Resolution of Oxaziridines via Chiral Bifunctional Guanidine- Catalyzed Enantioselective α?Hydroxylation of β?Keto Esters, Org. Lett.2016, 18, 3602?3605.

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