Issue 41, 2024
From the journal:

Chemical Communications

Two structurally new Lindqvist hexaniobate-templated silver thiolate clusters†

Zichen Zhao,a   Mengyun Zhao,a   Lan Deng,*a   Qing Li,a   Jing Zhang,a   Haifeng Su,b   Hongjin Lv ORCID logo *a  and  Guo-Yu Yang ORCID logo a  

* Corresponding authors

a MOE Key Laboratory of Cluster Science, Beijing Key Laboratory of Photoelectric/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, P. R. China
E-mail: hlv@bit.edu.cn, landeng@bit.edu.cn

b College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China

Abstract

Two structurally new Lindqvist hexaniobate-templated silver thiolate clusters, [Nb6O19@Ag45(iPrS)23(CH3COO)14] (Ag45) and (H3O)4[Nb6O19@Ag41KS2.5O2(H2O)7.5(iPrS)24(CH3COO)5] (Ag41), were synthesized using a facile one-pot solvothermal approach. Single crystal X-ray diffraction analyses revealed the presence of a classical Lindqvist-type [Nb6O19]8− anion template, with iPrS− and CH3COO− surface-protecting ligands in both silver clusters, which can further form two-dimensional Ag45 assembly and one-dimensional Ag41 chain packing structures. Both Ag45 and Ag41 clusters exhibited intriguing photothermal conversion properties and temperature-dependent emission behavior.

Graphical abstract: Two structurally new Lindqvist hexaniobate-templated silver thiolate clusters

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Article information

DOI
https://doi.org/10.1039/D4CC00681J
Article type
Communication
Submitted
09 Feb 2024
Accepted
23 Apr 2024
First published
23 Apr 2024

Chem. Commun., 2024,60, 5415-5418

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Two structurally new Lindqvist hexaniobate-templated silver thiolate clusters

Z. Zhao, M. Zhao, L. Deng, Q. Li, J. Zhang, H. Su, H. Lv and G. Yang, Chem. Commun., 2024, 60, 5415 DOI: 10.1039/D4CC00681J

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