A reduced polyoxometalate-encapsulated organo cobalt modified phosphate framework for improving photocatalytic reduction of CO2

Yinhua Zhu; Pinfang Yan; Lingtong Xu; Zeyu Du; Hua Mei; Yan Xu

doi:10.1039/D4DT00812J

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A reduced polyoxometalate-encapsulated organo cobalt modified phosphate framework for improving photocatalytic reduction of CO₂†

Yinhua Zhu,‡^a Pinfang Yan,‡^a Lingtong Xu,^a Zeyu Du,^a Hua Mei*^a and Yan Xu

*^a

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* Corresponding authors

^a College of Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211800, P. R. China
E-mail: lingtongxu@njtech.edu.cn

Abstract

A reduced polyoxometalate-based organo-metallophosphate (MOPO) framework formulated as [Co₄(PO₄)(C₇H₈N₄)₆](PW^VI₁₀W^V₂O₄₀) (Co-PO₄-PW₁₂) with an ultra-high CO production rate of 13 676 μmol g⁻¹ h⁻¹ has been presented through photocatalytic CO₂ reduction investigations.

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Article information

DOI: https://doi.org/10.1039/D4DT00812J
Article type: Communication
Submitted: 19 Mar 2024
Accepted: 10 Apr 2024
First published: 11 Apr 2024

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Dalton Trans., 2024,53, 7257-7262

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A reduced polyoxometalate-encapsulated organo cobalt modified phosphate framework for improving photocatalytic reduction of CO₂

Y. Zhu, P. Yan, L. Xu, Z. Du, H. Mei and Y. Xu, Dalton Trans., 2024, 53, 7257 DOI: 10.1039/D4DT00812J

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