From the journal:

Inorganic Chemistry Frontiers

Controlling the structural and adsorption features of polyoxovanadate-based metal–organic clusters by adjustable template effect†

Yan-Hu Wang,‡a   Ke-Wei Tong,‡a   Chao-Qin Chen,a   Jing Du,b   Guo-Ping Yang ORCID logo c  and  Peng Yang ORCID logo *a  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Advanced Catalytic Engineering Research Center of the Ministry of Education, Hunan University, Changsha 410082, China
E-mail: pengyang216@hnu.edu.cn

b College of Chemistry and Materials Science, Testing and Analysis Center, Hebei Normal University, Shijiazhuang 050024, China

c Jiangxi Province Key Laboratory of Synthetic Chemistry, Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, East China University of Technology, Nanchang 330013, China

Abstract

Templated synthesis in polyoxometalate chemistry offers the advantages not only of improving production efficiency but also of accessing unknown structures as well. In this contribution, the template effect of the sulfate group unlocked an unprecedented polyoxovanadate-based metal–organic cluster (POV-MOC). More importantly, such a template effect is adjustable by means of several strategies, for instance, introduction of exogenous metal ions, regulation of mixed solvent systems, and bi-functionalization of organic linkers. Using such strategies, the structure of the POV-MOC matrix was able to be modified specifically on a local domain or completely remodelled into an unusual nanocapsule. Aside from the contribution to the structural evolution of as-made POV-MOCs, the tunable template effect could also be used to control of their adsorption properties, establishing a new route for the customization of function-oriented POV-MOCs.

Graphical abstract: Controlling the structural and adsorption features of polyoxovanadate-based metal–organic clusters by adjustable template effect

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Article information

DOI
https://doi.org/10.1039/D4QI00254G
Article type
Research Article
Submitted
26 Jan 2024
Accepted
25 Mar 2024
First published
26 Mar 2024

Inorg. Chem. Front., 2024, Advance Article

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Controlling the structural and adsorption features of polyoxovanadate-based metal–organic clusters by adjustable template effect

Y. Wang, K. Tong, C. Chen, J. Du, G. Yang and P. Yang, Inorg. Chem. Front., 2024, Advance Article , DOI: 10.1039/D4QI00254G

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