Issue 32, 2024
From the journal:

Chemical Communications

Dioxane promoted photochemical O-alkylation of 1,3-dicarbonyl compounds beyond carbene insertion into C–H and C–C bonds†

Xinlong Zhou,a   Jingjing Jiang,a   Min Zhang,a   Qingqing Wu,a   Keyong Zhu,a   Dongjie Shi,a   Sensen Hou,a   Jingjing Zhao*a  and  Pan Li ORCID logo *a  

* Corresponding authors

a College of Chemistry and Molecular Sciences, Henan University, Kaifeng 475004, P. R. China
E-mail: zhaojingjing@henu.edu.cn, panli@henu.edu.cn

Abstract

A photochemical synthesis of enol ethers and furan-3(2H)-ones from 1,3-dicarbonyl compounds and aryl diazoacetates has been developed. Significantly, 1,4-dioxane promoted O-alkylation of various 1,3-dicarbonyl compounds beyond previous carbene insertion into C–H and C–C bonds has been disclosed.

Graphical abstract: Dioxane promoted photochemical O-alkylation of 1,3-dicarbonyl compounds beyond carbene insertion into C–H and C–C bonds

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Article information

DOI
https://doi.org/10.1039/D4CC00778F
Article type
Communication
Submitted
17 Feb 2024
Accepted
19 Mar 2024
First published
19 Mar 2024

Chem. Commun., 2024,60, 4330-4333

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Dioxane promoted photochemical O-alkylation of 1,3-dicarbonyl compounds beyond carbene insertion into C–H and C–C bonds

X. Zhou, J. Jiang, M. Zhang, Q. Wu, K. Zhu, D. Shi, S. Hou, J. Zhao and P. Li, Chem. Commun., 2024, 60, 4330 DOI: 10.1039/D4CC00778F

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