A scandium metalloligand supported Ni(0) complex with a heterobimetallocycle: versatile reactivity with unsaturated bonds

Lei Ma; Xiaowei Pan; Dongjing Hong; Huayi Fang; Peng Cui

doi:10.1039/D4CC00547C

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A scandium metalloligand supported Ni(0) complex with a heterobimetallocycle: versatile reactivity with unsaturated bonds†

Lei Ma,^a Xiaowei Pan,^b Dongjing Hong,^a Huayi Fang

*^b and Peng Cui

*^a

Author affiliations

* Corresponding authors

^a Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, S 189, Jiuhua Road, Wuhu, Anhui 241002, P. R. China
E-mail: pcui@ahnu.edu.cn

^b School of Materials Science and Engineering, Nankai University, No. 38 Tongyan Road, Haihe Education Park, Tianjin 300350, P. R. China
E-mail: hfang@nankai.edu.cn

Abstract

A N₂-bridged tetranuclear Sc(III)–Ni(0) complex featuring a Ni → Sc interaction and a 4-membered [Sc–N–C–Ni] ring was synthesized and characterized. Bimetallic reactivity was demonstrated via reactions with a series of unsaturated compounds containing N [triple bond, length as m-dash] C, CN, CC, C [double bond, length as m-dash] O and NN bonds.

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DOI: https://doi.org/10.1039/D4CC00547C
Article type: Communication
Submitted: 03 Feb 2024
Accepted: 14 Mar 2024
First published: 18 Mar 2024

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Chem. Commun., 2024,60, 4222-4225

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A scandium metalloligand supported Ni(0) complex with a heterobimetallocycle: versatile reactivity with unsaturated bonds

L. Ma, X. Pan, D. Hong, H. Fang and P. Cui, Chem. Commun., 2024, 60, 4222 DOI: 10.1039/D4CC00547C

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Chemical Communications

A scandium metalloligand supported Ni(0) complex with a heterobimetallocycle: versatile reactivity with unsaturated bonds†

Abstract

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A scandium metalloligand supported Ni(0) complex with a heterobimetallocycle: versatile reactivity with unsaturated bonds

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