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Layered coordination polymer with two-dimensional covalent bismuth-organic networks: Semiconductor and lithium ion storage

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Abstract

Single crystals of a bismuth-based coordination polymer (CP) with carboxyl-thiol ligands, [Bi(C8H2O4S2) (C2H8N)]n (Bi-DSBDC-DMA, DMBDC = 2,5-disulfur-1,4-dicarboxylate, DMA = dimethylamine), have been successfully synthesized. X-ray diffraction analysis reveals that Bi-DSBDC-DMA possesses a layered structure, with two-dimensional (2D) Bi-DSBDC networks alternating with layers composed of dimethylamine ions. This material demonstrates semiconducting properties, featuring an optical bandgap of 2.2 eV and an electrical conductivity of 2 × 10−8 S/cm. Furthermore, electrodes based on this material exhibit a capacity of 250 mAh/g after 200 cycles for lithium-ion storage.

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Acknowledgement

This work was financially supported by the Research Projects of Department of Education of Guangdong Province (No. 2023KTSCX319), and the National Natural Science Foundation of China (No. 92372114).

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Author notes

  1. Mu-Qing Li and Yulin Cao contributed equally to this work.

Authors and Affiliations

  1. School of Materials Science and Environmental Engineering, Shenzhen Polytechnic University, Shenzhen, 518055, China

    Mu-Qing Li & Hua Cheng

  2. Industrial Training Center, Shenzhen Polytechnic University, Shenzhen, 518055, China

    Weimin Yang

  3. Department of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen, 518055, China

    Mu-Qing Li, Yulin Cao & Zhouguang Lu

  4. Department of Chemistry, Southern University of Science and Technology, Shenzhen, 518055, China

    Lei Qin

Authors
  1. Mu-Qing Li
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  2. Yulin Cao
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  3. Lei Qin
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  4. Hua Cheng
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  5. Weimin Yang
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  6. Zhouguang Lu
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Corresponding authors

Correspondence to Hua Cheng, Weimin Yang or Zhouguang Lu.

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12274_2023_6367_MOESM1_ESM.pdf

Layered coordination polymer with two-dimensional covalent bismuth-organic networks: Semiconductor and lithium ion storage

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Li, MQ., Cao, Y., Qin, L. et al. Layered coordination polymer with two-dimensional covalent bismuth-organic networks: Semiconductor and lithium ion storage. Nano Res. 17, 2181–2185 (2024). https://doi.org/10.1007/s12274-023-6367-6

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  • DOI: https://doi.org/10.1007/s12274-023-6367-6

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