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Synthesis and Exploration of Barium Stannate–Zirconate BaSn1–xZrxO3 (0 ≤ X ≤ 1) Solid Solutions as Photocatalysts Inorg. Chem. (IF 4.6) Pub Date : 2024-03-27 Tarek Alammar, Anja-Verena Mudring
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A Room-Temperature Strategy to Synthesize Ce/Tb-Codoped NaYF4 Nanoparticles with a Photoluminescence Quantum Yield Exceeding 50% Inorg. Chem. (IF 4.6) Pub Date : 2024-03-27 Jinjian Wei, Mengxin Liu, Xinan Shi, Daocheng Pan
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IZCp and PZCp: Redox Non-innocent Cyclopentadienyl Ligands as Electron Reservoirs for Sandwich Complexes Inorg. Chem. (IF 4.6) Pub Date : 2024-03-27 Hyeonjeong Choi, Seunghyuk Yoo, Hayoung Song, Eunsung Lee
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Perimidocarbene-Based Tetradentate Platinum(II) Complexes with an Unexpectedly Negligible 3MLCT Character Inorg. Chem. (IF 4.6) Pub Date : 2024-03-27 Guijie Li, Yuankuo Liu, Kewei Xu, Chengyao Zhang, Jianqiang Chen, Qingshan Chu, Yun-Fang Yang, Yuanbin She
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Syntheses, Crystal Structures, and Electronic Structures of Quaternary Group IV-Selenide Semiconductors Inorg. Chem. (IF 4.6) Pub Date : 2024-03-27 Subhendu Jana, Eric Gabilondo, Scott McGuigan, Paul A. Maggard
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Selective Hydrolysis of Ovalbumin by Zr-Based Lacunary Polyoxotungstate in Surfactant Solutions Inorg. Chem. (IF 4.6) Pub Date : 2024-03-26 Malihe Babaei Zarch, Maryam Bazargan, Masoud Mirzaei
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Discovery of Excellent Ultraviolet Nonlinear Optical Materials in Chlorates and Bromates with Highly Stereochemically Active Lone Pairs Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-27 Chun-Li Hu, Qian-Qian Chen, Fang Kong, Jiang-Gao Mao
The discovery of short-wave ultraviolet (SWUV, λPM < 266 nm, PM = phase-matching) and deep ultraviolet (DUV, λPM < 200 nm) nonlinear optical (NLO) crystals is urgently required and full of challenge. Unlike the conventional strategy of using π-conjugated groups (such as BO3) as core motifs for constructing UV NLO crystals, herein the long-neglected stereochemically active lone pair (SCALP) groups ClO3
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Large-scale fabrication of ZIF-derived electrocatalysts toward industrial oxygen evolution Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-27 Liangjun Chen, Zhuowen Huangfu, Xue-Lin Yang, Hang Lei, Zilong Wang, Wenjie Mai
The laboratory-scale regarding catalyst synthesis is far from reaching the expectations of industrial-scale water electrolysis, and the bottleneck is the large-scale preparation of electrocatalysts. Herein, a cheap, efficient, and durable electrocatalyst (Mo-Co-O-ZIF) with two-dimensional nanosheet arrays in situ grown on pre-oxidized nickel foam is successfully synthesized through a time and energy-saving
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Phosphonate-substituted porphyrins as efficient, cost-effective and reusable photocatalysts Dalton Trans. (IF 4.0) Pub Date : 2024-03-26 Azhar Kechiche, Shaymaa AL SHEHIMY, Lhoussain Khrouz, Andrei Vladimirovich Cheprakov, Cyrille Monnereau, Christophe Bucher, Stephane Parola, Alla Bessmertnykh-Lemeune, Yoann Rousselin, Habib Nasri
Recent advances in visible light photocatalysis represent a significant stride towards sustainable catalytic chemistry. However, their successful implementation in fine chemical production remains challenging and requires careful optimization of available photocatalysts. Our work aims to structurally modify bioinspired porphyrin catalysts, addressing issues related to their laborious synthesis and
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Copper-catalysed electrophilic carboamination of terminal alkynes with benzyne looked at through the computational lens Dalton Trans. (IF 4.0) Pub Date : 2024-03-27 Sven Tobisch
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Structure and morphology of red pigments based on sepiolite Dalton Trans. (IF 4.0) Pub Date : 2024-03-27 I. Carrillo, E. Atanes-Sánchez, F. Fernández-Martínez
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Nonionic polymer and amino acid-assisted synthesis of ZSM-5 nanocrystals and their catalytic application in alkylation of 2-methylnaphthalene Dalton Trans. (IF 4.0) Pub Date : 2024-03-27 Junling Zhan, Ying Wang, Tengfei He, Luyang Sheng, Banghao Wu, Qun Liu, Mingjun Jia, Yu Zhang
Synthesis of nanosized ZSM-5 zeolites with high crystallinity and suitable acidity is very significant for its great potential in various catalytic applications. Herein, a series of zeolite ZSM-5 crystals with different particle sizes and SiO2/Al2O3 ratios (10–30) were synthesized by a temperature-varying two-step crystallization method in a concentrated gel system containing ʟ-lysine and/or polyvinylpyrrolidone
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Photocatalytic conversion of CO2 to CO by Ru(II) and Os(II) octahedral complexes: a DFT/TDDFT study Dalton Trans. (IF 4.0) Pub Date : 2024-03-22 Athanassios C. Tsipis, Antonia A. Sarantou
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Azidomethyl-Bisoxadiazol- Linked-1,2,3-Triazole-(ABT)-Based Potential Liquid Propellant and Energetic Plasticizer† Dalton Trans. (IF 4.0) Pub Date : 2024-03-26 Sohan Lal, Richard J. Staples, Jean'ne M. Shreeve
A scalable synthesis of azidomethyl bisoxadiazol linked-1,2,3-triazole-(ABT) based potential liquid propellant and energetic plasticizer is obtained from commercially available diaminomaleonitrile in excellent yield. Newly synthesized compounds were fully characterized by various spectroscopic techniques. These materials exhibit good densities (1.77 gcm-3) and high thermal stabilities (Td = 181 °C)
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Cu(dppf) complexes can be synthesized from Cu-exchanged solids and enable a quantification of the Cu-accessibility by 31P MAS NMR spectroscopy Dalton Trans. (IF 4.0) Pub Date : 2024-03-22 Elif Kaya, Daniel Dittmann, Maximilian Schmidt, Michael Dyballa
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Complexation of Hexavalent Neptunium(VI) with Oxydiacetic Acid and Its Amide Derivatives in Aqueous Solution: Spectrophotometry and DFT Calculations Inorg. Chem. (IF 4.6) Pub Date : 2024-03-26 Lei Xu, Xiao-Kun Zhao, Hong Cao, Han-Shi Hu, Jun Li, Jing Chen, Chao Xu
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Understanding the Growth Mechanism of HgTe Colloidal Quantum Dots through Bilateral Injection Inorg. Chem. (IF 4.6) Pub Date : 2024-03-26 Hao Yang, Qiong Zhang, Ruiguang Chang, Zhenghui Wu, Huaibin Shen
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Rational Design of NiCo-borate/GO Heterojunction as a High-Performance Supercapacitor Electrode Inorg. Chem. (IF 4.6) Pub Date : 2024-03-26 Pinghua Chen, Huanghuang Song, Zilong Zou, Hualin Jiang, Xinman Tu, Weiqiang Zhou, Jun Zhou, Tingliang Liu, Guanghui Wu, Haiying Zhou
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Study on a Highly Thermostable Dy3+-Activated Borophosphate Phosphor Inorg. Chem. (IF 4.6) Pub Date : 2024-03-26 Conglin Liu, Youkui Zheng, Yue Qin, Lulu Liang, Shuqing Yang, Hong Li, Hongming Jiang, Xiaoyang Zhao, Shanlin Liu, Hongzhi Zhang, Jing Zhu
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Fine-Tuning Optoelectronic Features in Organic–Inorganic Hybrid Metal Halides: A Focus on the Phenylbutanammonium Series Inorg. Chem. (IF 4.6) Pub Date : 2024-03-26 Shihui He, Kunjie Liu, Yan Xiong, An Hou, Xianlong Zhao, Jing Zhao, Quanlin Liu
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Surface Passivation toward Multiple Inherent Dangling Bonds in Indium Phosphide Quantum Dots Inorg. Chem. (IF 4.6) Pub Date : 2024-03-25 Zhe Sun, Qinggang Hou, Jiahua Kong, Keke Wang, Ruiling Zhang, Feng Liu, Jiajia Ning, Jianguo Tang, Zhonglin Du
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PtCu Alloy-Modified Triptycene-Based Polymer with Charge Separation for Photocatalytic Hydrogen Evolution from Water/Seawater Inorg. Chem. (IF 4.6) Pub Date : 2024-03-25 Jian Zhang, Xinglong Li, Zheng Peng, Xiuzheng Deng, Yanan Wang, Zhongyu Li, Qian Liang
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Inorganic–Organic Hybrid Layered Semiconductor AgSePh: Quasi-Solution Synthesis, Optical Properties, and Thermolysis Behavior Inorg. Chem. (IF 4.6) Pub Date : 2024-03-25 Kewei Gu, Tingting Wang, Guowei Yang, Nan Yu, Chengchao Du, Junli Wang
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Strategy of Charge Compensation for High-Performance Ni2+-Activated MgAl2O4 Spinel Near-Infrared Phosphor Synthesis via the Sol–Gel Combustion Method Inorg. Chem. (IF 4.6) Pub Date : 2024-03-25 Yu Deng, Fengmei Zhu, Yuan Gao, Jianbei Qiu
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Copper Electrocatalyst Produced by Cu2(OH)2CO3-Mediated In Situ Deposition for Diluted CO2 Reduction to Multicarbon Products Inorg. Chem. (IF 4.6) Pub Date : 2024-03-24 Qiankang Zhang, Zhanbo Si, Ying Zhang, Yilin Deng, Xiaojie She, Qing Yu
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Enhancing Iron(III) Oxide Photoelectrochemical Water Splitting Performance Using Defect Engineering and Heterostructure Construction Inorg. Chem. (IF 4.6) Pub Date : 2024-03-22 Juan Wu, Ming Meng, Xiao-Di Du, Mingjie Li, Lin Jin, Weisheng Liu
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Effects of weak intramolecular interactions and distortions from trigonal prismatic coordination on the magnetic properties of zero-field Co(II) single-ion magnets Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-26 Ben Zhang, Yang Zhou, Hao-Yi Huang, Xiao-Le Zhang, Yi Xiang, Yanbo Shi, Chennan Zhang, Aihua Yuan, Xingwei Cai, Lei Chen, Yi-Quan Zhang, Zhao-Bo Hu
The mononuclear cobalt(II) complexes [Co(LN8)](BPh4)2∙C4H10O (1-BPh4) and [Co(LN8)](NO3)2∙CH3CN (2-NO3) (LN8 = 1,4,7,10-tetrakis(2-pyridinemethyl)-1,4,7,10-tetraaza-cyclododecane) have been synthesized and fully characterized. They differ well beyond a formal replacement of the counter anions, with their Co(II) centers in significantly different coordination geometries. In 1-BPh4, the Co(II) ion is
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Recycling Primary Lithium Batteries Using a Coordination Chemistry Approach: Recovery of Lithium and Manganese Residues in the Form of Industrially Important Materials Dalton Trans. (IF 4.0) Pub Date : 2024-03-26 Rafał Petrus, Adrian Kowaliński, Tadeusz Lis
In this study, we have investigated the potential use of post-consumer primary lithium metal batteries (LMBs) commonly used in portable electronic devices to recover lithium and manganese in the form of industrially important materials. A direct reaction of lithium-containing electronic waste with natural-source ester – methyl salicylate combined with a wide range of aliphatic alcohols has been used
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Tuning of surface oxygen vacancies for enhancing photocatalytic performance under visible light irradiation in Sb2WO6 nanostructures Dalton Trans. (IF 4.0) Pub Date : 2024-03-26 Manisha Sharma, Rahul Singh, Anitya Sharma, Venkata Krishnan
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Unusual redox stability of pentavalent uranium with hetero-bifunctional phosphonocarboxylate: Insight into aqueous speciation Dalton Trans. (IF 4.0) Pub Date : 2024-03-26 Ashutosh Srivastava, Musharaf Ali, Rama Mohana Rao Dumpala, Sumit Kumar, Pranaw Kumar, Neetika Rawat, Prasanta Kumar Mohapatra
The +5 state is an unusual oxidization state of uranium due to its instability in the aqueous phase. As a result, gaining information about its aqueous speciation is extremely difficult. The present work is an attempt in that direction and it provides insight into the existence of new pentavalent species in the presence of hetero-bifunctional phosphonocarboxylate (PC) chelators, other than the carbonate
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A Bis(PCN) Palladium Pincer Complex with a Remarkably Planar 2,5-Diarylpyrazine Core Dalton Trans. (IF 4.0) Pub Date : 2024-03-26 Derek W. Leong, Yanwu Shao, Zhen Ni, Nattamai Bhuvanesh, Oleg V. Ozerov
A bimetallic Pd complex of a bis(pincer) with a diarylpyrazine core has been prepared. The complex demonstrates near-perfect coplanarity of the aromatic core, is fluorescent under UV irradiation, and displays two quasi-reversible reduction events.
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Catalytic Dinitrogen Reduction to Hydrazine and Ammonia using Cr(N2)2(diphosphine)2 Complexes Dalton Trans. (IF 4.0) Pub Date : 2024-03-26 Charles H. Beasley, Olivia L. Duletski, Ksenia S Stankevich, Navamoney Arulsamy, Michael Thomas Mock
We report the synthesis and characterization of trans-[Cr(N2)2(depe)2] (depe = Et2PCH2CH2PEt2). trans-[Cr(N2)2(depe)2] and the structurally similar complex trans-[Cr(N2)2(dmpe)2] (dmpe = Me2PCH2CH2PMe2) catalyze the reduction of N2 to form N2H4 and NH3 at room temperature using the proton-coupled electron transfer reagent SmI2 with ethylene glycol or H2O as proton sources. A catalyst comparison under
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Inorganic−organic-hybrid Cu−dipyridyl semiconducting polymers based on redox-active cluster [SFe3(CO)9]2−: filling the gap in iron carbonyl chalcogenide polymers Dalton Trans. (IF 4.0) Pub Date : 2024-03-26 Ming-Chi Hsu, Ru Yan Lin, Tzu-Yen Sun, Yu-Xin Huang, Min-Sian Li, Yu-Huei Li, Hui-Lung Chen, Minghuey Shieh
The construction of sulfur-incorporated cluster-based coordination polymers was limited and underexplored due to the lack of efficient synthetic routes. Herein, we reported the facile mechanochemical ways toward a new series of SFe3(CO)9-based dipyridyl-Cu polymers by three-component reactions of [Et4N]2[SFe3(CO)9] ([Et4N]2[1]) and [Cu(MeCN)4][BF4] with conjugated or conjugation-interrupted dipyridyl
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Triclinic La7Zn2P11 with P3−, P24−, and P35− units: a combined study by 31P solid-state NMR spectroscopy and single crystal X-ray diffraction Dalton Trans. (IF 4.0) Pub Date : 2024-03-23 Jutta Kösters, Christopher Benndorf, Tobias Uesbeck, Thomas Wiegand, Hellmut Eckert, Hannes Lincke, Rainer Pöttgen
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Carbon quantum dots-decorated g-C3N4 composite as a sulfur hosting material for lithium-sulfur batteries Dalton Trans. (IF 4.0) Pub Date : 2024-03-25 Yang Liu, Dandan Cai, Feng Zheng, Ziwei Qin, Ying Li, Wenxian Li, Aijun Li, Yufeng Zhao, Jiujun Zhang
Although lithium-sulfur (Li-S) batteries have attracted strong consideration on their fundamental mechanism and energy applications, the inferior cycling performance and low reaction rate caused by the “shuttle effect” and the sluggish reaction kinetics of lithium polysulfides (LiPSs) impedes their practical application. In this work, the graphited C3N4 (g-C3N4) assembled with highly-dispersed nitrogen-containing
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Unusual reaction in nitromethane solution: use of Cp*Rh moiety to form prussian blue analogues Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-26 Hui-Rong Ma, Liang-Chen Liu, Yuluan Liao, Hua-Tian Shi, Po Sun, Weibin Yu
The direct decomposition of nitromethane into nitrile compounds poses a significant challenge due to the occurrence of severe side reactions. In this study, we present a novel and gentle methodology for converting primary nitromethane into nitriles using [Cp*RhCl2]2. This reaction is characterized by its simplicity and convenience under mild conditions. Moreover, the resulting nitrile serves as a direct
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Rational design for broad near-infrared emission from a two-sited Rb2LiAlF6:Cr3+ phosphor with high efficiency and thermal stability for spectroscopic applications Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-26 Song Qing, Jing Wan, Tao Yang, Qiang Zhou, Yayun Zhou, Zhengliang Wang, Dawei Wen, Mingmei Wu
The exploration of high-performance near-infrared phosphor has attracted a widespread attention. In this work, a brand new Rb2LiAlF6:Cr3+ (denoted as RLAF:Cr) phosphor has been constructed by the substitutions of Al3+ ions with Cr3+ ions. The evidences have shown that two sets of near-infrared emission bands, which originated from two types of Cr3+ sites, were observed upon blue light excitation. These
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Structural and Adsorption Features of Polyoxovanadate-Based Metal–Organic Clusters Controlled by Adjustable Template Effect Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-26 Yan-Hu Wang, Ke-Wei Tong, Chao-Qin Chen, Jing Du, Guo-Ping Yang, Peng Yang
Templated synthesis in polyoxometalate chemistry offers the advantages not only of improving production efficiency, but of accessing to unknown structures as well. In this contribution, the template effect of sulfate group unlocked an unprecedented polyoxovanadate-based metal–organic cluster (POV-MOC). What is more important, such template effect is adjustable by means of several strategies, for instance
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Modulating Mn self-reduction and multimodal luminescence in CaSb2O6 through La3+ doping for quadruple-mode dynamic anti-counterfeiting and optical temperature sensing applications Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-25 Xinmin Zhang, Fenzhong Long, Lu Xie, Jiawei Fu, Kaian Shan, Huihui Fei
Luminescent materials act as a key role in the field of optical anti-counterfeiting. Developing multimode, multi-color dynamic phosphors, making the optical anti-counterfeiting more advanced and more practical, remains a great challenge. In this paper, multimode luminescence (PL, PersL, TL, PSL, PSPL), dynamic multi-color emission phosphors based on single CaSb2O6 (CSO) host doped with manganese ion
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Two-dimensional spin crossover coordination polymers based on 1,1,2,2-tetra(pyridin-4-yl)ethene ligand Dalton Trans. (IF 4.0) Pub Date : 2024-03-26 Mengling Wu, Yan-Cong Chen, Ze-Yu Ruan, Zhao-Ping Ni, Si-Guo Wu, Ming-Liang Tong
A series of two-dimensional (2D) spin crossover coordination polymers (SCO-CPs) [FeII(TPE)(NCX)2]·solv (1: X = BH3, solv = H2O·2CH3OH·DMF; 2: X = Se, solv = H2O·2CH3OH·0.5DMF; 3: X = S, solv = H2O·2CH3OH·0.5DMF) were synthesized by employing 1,1,2,2-tetra(pyridin-4-yl)ethene (TPE) and pseudohalide (NCX−) coligands. Magnetic measurements indicate that complexes 1−3 exhibit SCO behaviors with diminishing
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Transition Metal Complexes of the (2,2,2-Trifluoroethyl)phosphinate NOTA Analogue as Potential Contrast Agents for 19F Magnetic Resonance Imaging Dalton Trans. (IF 4.0) Pub Date : 2024-03-26 Filip Koucký, Tereza Dobrovolná, Jan Kotek, Ivana Cisarova, Jana Havlickova, Alan Liška, Vojtech Kubicek, Petr Hermann
A new hexadentate 1,4,7-triazacyclononane-based ligand bearing three coordinating methylene-(2,2,2-trifluoroethyl)phosphinate pendant arms was synthesized and its coordination behaviour towards selected divalent (Mg2+, Ca2+, Mn2+, Fe2+, Co2+, Ni2+, Cu2+, Zn2+) and trivalent (Cr3+, Fe3+, Co3+) transition metal ions was studied. The ligand forms stable complexes with late divalent transition metal ions
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Activating a High-Spin Iron(II) Complex to Thermal Spin-Crossover with an Inert Non-Isomorphous Molecular Dopant Dalton Trans. (IF 4.0) Pub Date : 2024-03-26 Malcolm Halcrow, Hari Babu Vasili, Christopher M. Pask, Alexander N Kulak, Oscar Cespedes
[Fe(bpp)2][ClO4]2 (bpp = 2,6-bis{pyrazol-1-yl}pyridine; monoclinic, C2/c) is high-spin between 5-300 K, and crystallises with a highly distorted molecular geometry that lies along the octahedral−trigonal prismatic distortion pathway. In contrast, [Ni(bpp)2][ClO4]2 (monoclinic, P21) adopts a more regular, near-octahedral coordination geometry. Gas phase DFT minimisations (ω-B97X-D/6-311G**) of [M(bpp)2]2+
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Dual FGFR-targeting and pH-activable Ruthenium-Peptide Conjugates for targeted therapy of Breast Cancer Dalton Trans. (IF 4.0) Pub Date : 2024-03-26 João Franco Machado, Marco Sá, Inês Pires, Miguel Tarita da Silva, Fernanda M. Marques, Jaime A. S. Coelho, Filipa Mendes, Maria Fátima Minas da Piedade, Miguel Machuqueiro, María Angeles Jiménez, Maria Helena Garcia, João D. G. Correia, Tânia S. Morais
Dysregulation of Fibroblast Growth Factor Receptors (FGFRs) signaling has been associated with breast cancer, yet employing FGFR-targeted delivery systems to improve the efficacy of cytotoxic agents is still sparsely exploited. Herein, we report four new bi-functional ruthenium-peptide conjugates (RuPCs) with FGFR-targeting and pH-dependent releasing abilities, envisioning the selective delivery of
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Polyoxometalate-Based Reticular Materials for Proton Conduction: From Rigid Frameworks to Flexible Networks Dalton Trans. (IF 4.0) Pub Date : 2024-03-26 Xiang Li, Shengchao Chai, Haolong Li
Proton conductors play a crucial role in energy and electronic technologies, thus attracting extensive research interest. Recently, reticular chemistry has propelled the development of reticular materials with framework or network structures, which contains tunable proton transport pathways to achieve optimal conducting performance. Polyoxometalates (POMs), as a class of high proton conducting units
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Designing One-compartment H2O2 Fuel Cell Using Electroactive Phenalenyl-based [Fe2(hnmh-PLY)3] Complex as the Cathode Material Dalton Trans. (IF 4.0) Pub Date : 2024-03-26 Nisha Kamboj, Ayan Dey, Sunita Birara, Moumita Majumder, Srijan Sengupta, Ramesh K. Metre
The sustainable chemical energy of H2O2 as a fuel and an oxidant in an advantageous single-compartment fuel cell design can be converted into electric energy, which requires molecular engineering to design suitable cathodes for lowering the high overpotential associated with H2O2 reduction. The present work covers the synthesis, and structural characterization of a novel cathode material, [FeIII2(hnmh-PLY)3]
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Heptanuclear Mixed-Valence Co4IIICo3II Molecular Wheel─A Molecular Analogue of Layered Double Hydroxides with Single-Molecule Magnet Behavior and Electrocatalytic Activity for Hydrogen Evolution Reactions Inorg. Chem. (IF 4.6) Pub Date : 2024-03-25 Biplab Biswas, Anjila I. Siddiqui, Mithun Chandra Majee, Swadhin Kumar Saha, Biswajit Mondal, Rajat Saha, Carlos J. Gómez García
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Unraveling the Remarkable Influence of Substituents on the Emission Variation and Circularly Polarized Luminescence of Dinuclear Aluminum Triple-Stranded Helicates Inorg. Chem. (IF 4.6) Pub Date : 2024-03-25 Kodai Ueno, Yuto Konishi, Luxia Cui, Takunori Harada, Kohei Ishibashi, Takeru Konta, Atsuya Muranaka, Yoshio Hisaeda, Yu Hoshino, Toshikazu Ono
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Macrocyclic Copper(II) Complexes as Catalysts for Electrochemically Mediated Atom Transfer Inorg. Chem. (IF 4.6) Pub Date : 2024-03-25 Masnun Naher, Chuyi Su, Jeffrey R. Harmer, Craig M. Williams, Paul V. Bernhardt
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Simple to Quadruple Perovskite Transformation by Coordination Switching upon Solid-State Ion Exchange of NaNbO3 Inorg. Chem. (IF 4.6) Pub Date : 2024-03-24 Preeti Dahiya, Tapas Kumar Mandal
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Postsynthetic Installation of Lanthanide Cubane Clusters in a 3D Hydrogen-Bonded Framework of IrIII4ZnII4 Multicarboxylates Inorg. Chem. (IF 4.6) Pub Date : 2024-03-23 Supaphorn Thammakan, Nobuto Yoshinari, Marie Tsuchikawa, Apinpus Rujiwatra, Takumi Konno
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A Synergistic Bimetallic Ti/Co-Catalyzed Isomerization of Epoxides to Allylic Alcohols Enabled by Two-State Reactivity Inorg. Chem. (IF 4.6) Pub Date : 2024-03-22 Fangfang Li, Jialing Lan, Xin Li, Lung Wa Chung
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Third-Order Nonlinear Optical Modulation Behavior of Photoresponsive Bimetallic MOFs Inorg. Chem. (IF 4.6) Pub Date : 2024-03-22 Jiongjiong Yu, Yupei Sun, Kangshuai Geng, Jing Huang, Yang Cui, Hongwei Hou
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Polysubstitution Induced Centrosymmetric-to-Noncentrosymmetric Structural Transformation and Nonlinear-Optical Behavior: The Case of Na0.45Ag0.55Ga3Se5 Inorg. Chem. (IF 4.6) Pub Date : 2024-03-22 Jun Li, Jia-Nuo Li, Li-Yun Hu, Jun-Jie Ni, Wen-Dong Yao, Wenfeng Zhou, Wenlong Liu, Sheng-Ping Guo
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Synergistic Role of Hydrogen bond and Band degeneracy Leads to Enhanced X-ray Detection in HPIP-(NH4)0.7Cs0.3Br3•H2O Perovskites Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-25 Pengxiang Dong, Chensheng Lin, Xin Zhao, Yicong Lv, Ning Ye, Min Luo
Metal-free perovskites (MFPs) have emerged as a promising material for the development of eco-friendly, non-toxic, and wearable X-ray detectors. However, the advancement of MFPs has been hindered by several significant challenges, most notably their lower absorption coefficient and their susceptibility to oxidation and degradation in iodine-based detectors. To address these issues, this study proposes
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NH3 plasma etching derived porous N-doped carbon nanotubes with FeP nanoparticles and intrinsic carbon defects for boosting oxygen reduction in rechargeable Zn-air batteries Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-25 Bing Chen, Minjie Zhou, Na Zhang, Xianglin Deng, Haihua Yang
Modulating intrinsic activity and coupling with transition metal phosphides are encouraging strategies to enhance the electrochemical performance of carbon-based materials. In this study, N-doped carbon nanotubes were derived from polyaniline nanotubes upon the guiding growth by the micelles soft template comprised of Fe3+ ions and methyl orange. Phytic acid was employed to detain Fe3+ ions from washing
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Durable dielectric switching and photo-responsivity in a Dion–Jacobson hybrid perovskite semiconductor Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-25 Peng Wang, Xinling Li, Huang Ye, Qianwen Guan, Yifei Wang, Yaru Geng, Chengshu Zhang, Hang Li, Junhua Luo
Two-dimensional hybrid perovskite (2DHPs) semiconductors have shown great potential in multifunctional applications, especially dielectric switches and photoelectric detection owing to their diverse structural feasibility and excellent semiconducting features. However, most of the reported 2DHPs belong to the Ruddlesden–Popper (R–P) type, which unavoidably suffers from weak van der Waals interactions
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Beyond copper: examining the significance of His-mutations in mycobacterial GroEL1 HRCT for Ni(II) complex stability and formation Dalton Trans. (IF 4.0) Pub Date : 2024-03-25 Anna Rola, Arian Kola, Daniela Valensin, Oscar Palacios, Merce Capdevila, Elżbieta Gumienna-Kontecka, Sławomir Potocki
Recently, we have studied the coordination chemistry of the Cu(II)–histidine-rich C-terminal tail (HRCT) complex of the mycobacterial GroEL1 protein. The structure of this domain differs significantly compared to the well-known methionine-glycine-rich GroEL chaperonin – it was predicted that mycobacterial GroEL1 could play a significant role in the metal homeostasis of Mycobacteria, especially copper
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Competition mechanism of self-trapped excitons and Te4+ ions emission in the Te4+ doped vacancy-ordered double perovskite Rb2HfCl6 and its excellent properties Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-25 Ruxin Liu, Kaishun Zou, Guanglu Zhang, Min Feng, Mingxuan Li, Juncheng Liu
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Room temperature spin crossover properties in a series of mixed-anion Fe(NH2trz)3(BF4)2-x(SiF6)x/2 complexes Dalton Trans. (IF 4.0) Pub Date : 2024-03-25 Xinyu Yang, Alejandro Enriquez-Cabrera, Kane Jacob, Yannick Coppel, Lionel Salmon, Azzedine Bousseksou
A series of mixed-anion Fe(NH2trz)3(BF4)2-x(SiF6)x/2 spin crossover complexes is obtained modifying the reaction time but also using an increase amount of tetraethyl orthosilicate as the source for the production and the incorporation of SiF62- competing with the BF42- anions present in the mother solution. The increase of the SiF62- anion inclusion to the detriment of the BF4- counterpart induces
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1,1'-bis-(diphenylphosphino)ferrocene appended d8- and d10-configuration based thiosquarates: The molecular and electronic configurational insights into their sensitization and co-sensitization properties for dye sensitized solar cells Dalton Trans. (IF 4.0) Pub Date : 2024-03-25 Aparna Kushwaha, Devyani Srivastava, Om Prakash, Gabriele Kociok-Köhn, Suresh Gosavi, Ratna Chauhan, Mohd. Muddassir, Abhinav Kumar
Three new d8- and d10-configuration based 1,1'-bis(diphenylphosphino)ferrocene (dppf) appended thiosquarates complexes with general composition [M(mtsq)2dppf] (M = Ni2+ (NiL2); Zn2+ (ZnL2) and Cd2+ (CdL2)) (mtsq = 3-ethoxycyclobutenedione-4-thiolate) have been synthesized and characterized spectroscopically as well as in case of NiL2 by single crystal X-ray diffraction technique. The single crystal