skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Hetero-nanostructured materials for high-power lithium ion batteries

Journal Article · · Journal of Colloid and Interface Science
 [1]; ORCiD logo [2];  [3]
  1. Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Physical and Computational Sciences Directorate
  2. Iowa State Univ., Ames, IA (United States). Dept. of Chemical and Biological Engineering
  3. Ningbo Polytechnic, Ningbo (China). Chemical Engineering College

The development of high technology electrical devices increased the importance of higher power density or higher capacity at high current density. Especially, rapid charge/discharge issues remain problematic for electric vehicle commercialization. After extensive investigation, researchers introduced hetero-nanostructured materials to the field of lithium ion batteries (LIBs), aiming to enhance the power density or improve the capacity at high current density and life cycle capability. Hetero-nanostructured materials consist of current collectors and directly attached active nanomaterials. Carbon, carbon nanotube (CNT), graphene, Nickel (Ni), Copper (Cu) and Aluminum (Al) were used for current collector, aiming to improve the electron transfer and the cyclability, due to high electrical conductivity and superior buffering effects. Also, Hetero-nanostructure can produce a favorable lithium diffusion condition by creating a lithium diffusion pathway. This work presents an explanation of important factors for high power density or high capacity at high current density. It summarizes the capacity of electrode materials at high current density, including structural descriptions and material types.

Research Organization:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE; Natural Science Foundation of Ningbo (China)
Grant/Contract Number:
2017A610025; AC0576RL01830
OSTI ID:
1457745
Report Number(s):
PNNL-SA-135645; PII: S0021979718306738
Journal Information:
Journal of Colloid and Interface Science, Vol. 529, Issue C; ISSN 0021-9797
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 15 works
Citation information provided by
Web of Science

References (108)

Nanostructured electrodes for high-power lithium ion batteries journal July 2012
Nanostructured materials for advanced energy conversion and storage devices journal May 2005
Building better batteries journal February 2008
Challenges for Rechargeable Li Batteries journal February 2010
Issues and challenges facing rechargeable lithium batteries journal November 2001
Functional Materials for Rechargeable Batteries journal March 2011
3D Self-Supported Nanoarchitectured Arrays Electrodes for Lithium-Ion Batteries journal January 2012
Cotton-templated hierarchical porous structures for high power lithium rechargeable batteries journal January 2013
Materials for electrochemical capacitors journal November 2008
Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries journal February 2006
Recent developments in nanostructured anode materials for rechargeable lithium-ion batteries journal January 2011
Mesoporous Co 3 O 4 Nanowire Arrays for Lithium Ion Batteries with High Capacity and Rate Capability journal January 2008
Nanostructured Electrodes and the Low-Temperature Performance of Li-Ion Batteries journal January 2005
Surface modifications of electrode materials for lithium ion batteries journal February 2006
Improving the Electrochemical Performance of LiCoO2 Cathode by Nanocrystalline ZnO Coating journal January 2005
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review journal July 2017
Reviving the lithium metal anode for high-energy batteries journal March 2017
Suppression of lithium dendrite growth by introducing a low reduction potential complex cation in the electrolyte journal January 2016
High rate and stable cycling of lithium metal anode journal February 2015
Spatially heterogeneous carbon-fiber papers as surface dendrite-free current collectors for lithium deposition journal February 2012
Two-dimensional heterostructures for energy storage journal June 2017
Complex Nanostructures: Synthesis and Energetic Applications journal February 2010
Hybrid Nanorod-Polymer Solar Cells journal March 2002
Two-Dimensional Materials for Beyond-Lithium-Ion Batteries journal March 2016
Two-Dimensional Nanoarchitectures for Lithium Storage journal April 2012
High-performance lithium battery anodes using silicon nanowires journal December 2007
Advanced Materials for Energy Storage journal February 2010
Building one-dimensional oxide nanostructure arrays on conductive metal substrates for lithium-ion battery anodes journal January 2011
Cu3Si-doped porous-silicon particles prepared by simplified chemical vapor deposition method as anode material for high-rate and long-cycle lithium-ion batteries journal April 2017
An Analytical Method to Determine Tortuosity in Rechargeable Battery Electrodes journal January 2012
Synthesis of Cu3.8Ni/CoO and Cu3.8Ni/MnO nanoparticles for advanced lithium-ion battery anode materials journal December 2016
The Fermi level and the redox potential journal August 1985
Dendritic growth mechanisms in lithium/polymer cells journal September 1999
Electrochemical aspects of the generation of ramified metallic electrodeposits journal December 1990
The effects of current density and amount of discharge on dendrite formation in the lithium powder anode electrode journal April 2008
Metal Oxides and Oxysalts as Anode Materials for Li Ion Batteries journal March 2013
Interconnected hollow carbon nanospheres for stable lithium metal anodes journal July 2014
Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries journal September 2000
Ultrathin Spinel LiMn 2 O 4 Nanowires as High Power Cathode Materials for Li-Ion Batteries journal October 2010
Tailored Oxygen Framework of Li 4 Ti 5 O 12 Nanorods for High-Power Li Ion Battery journal March 2014
Spinel Li[sub 4]Ti[sub 5]O[sub 12] Nanowires for High-Rate Li-Ion Intercalation Electrode journal January 2007
Ultrathin mesoporous Co 3 O 4 nanosheets-constructed hierarchical clusters as high rate capability and long life anode materials for lithium-ion batteries journal June 2017
A Microwave Synthesis of Mesoporous NiCo 2 O 4 Nanosheets as Electrode Materials for Lithium-Ion Batteries and Supercapacitors journal November 2014
Facet-Selective Deposition of FeO x on α-MoO 3 Nanobelts for Lithium Storage journal November 2017
Porous ternary complex metal oxide nanoparticles converted from core/shell nanoparticles journal February 2016
Li ion battery materials with core–shell nanostructures journal January 2011
Synthesis and Electrochemical Performance of Nano-sized Li4Ti5O12 Coated with Boron-Doped Carbon journal April 2016
Nanosized Li[sub 4]Ti[sub 5]O[sub 12] Prepared by Molten Salt Method as an Electrode Material for Hybrid Electrochemical Supercapacitors journal January 2006
Effect of particle dispersion on high rate performance of nano-sized Li4Ti5O12 anode journal July 2007
Microsphere LiFe0.5Mn0.5PO4/C composite as high rate and long-life cathode material for lithium-ion battery journal April 2016
Rational Design of MnO/Carbon Nanopeapods with Internal Void Space for High-Rate and Long-Life Li-Ion Batteries journal May 2014
Mesoporous NiCo 2 O 4 Nanowire Arrays Grown on Carbon Textiles as Binder-Free Flexible Electrodes for Energy Storage journal December 2013
Core-shell yolk-shell Si@C@Void@C nanohybrids as advanced lithium ion battery anodes with good electronic conductivity and corrosion resistance journal February 2017
Design and Synthesis of Bubble-Nanorod-Structured Fe 2 O 3 –Carbon Nanofibers as Advanced Anode Material for Li-Ion Batteries journal February 2015
Encapsulation of Sn@carbon Nanoparticles in Bamboo-like Hollow Carbon Nanofibers as an Anode Material in Lithium-Based Batteries journal August 2009
A unique 2D-on-3D architecture developed from ZnMn2O4 and CMK-3 with excellent performance for lithium ion batteries journal October 2017
Synthesis of 2D-Mesoporous-Carbon/MoS 2 Heterostructures with Well-Defined Interfaces for High-Performance Lithium-Ion Batteries journal September 2016
There-dimensional porous carbon network encapsulated SnO 2 quantum dots as anode materials for high-rate lithium ion batteries journal November 2016
Carbon-Encapsulated Co 3 O 4 @CoO@Co Nanocomposites for Multifunctional Applications in Enhanced Long-life Lithium Storage, Supercapacitor and Oxygen Evolution Reaction journal December 2016
FeS2@C nanowires derived from organic-inorganic hybrid nanowires for high-rate and long-life lithium-ion batteries journal October 2016
Hierarchical flower-like C/NiO composite hollow microspheres and its excellent supercapacitor performance journal August 2017
Electrical Properties and Applications of Carbon Nanotube Structures journal April 2007
Electrical Properties of Carbon Nanotube Based Fibers and Their Future Use in Electrical Wiring journal March 2014
Nanostructured Hybrid Silicon/Carbon Nanotube Heterostructures: Reversible High-Capacity Lithium-Ion Anodes journal March 2010
Local-ordering MoO2 nanostructures within porous N-doped carbon nanotubes for high-rate reversible lithium storage journal February 2017
One-Pot Synthesis of Carbon Nanotube@SnO 2 −Au Coaxial Nanocable for Lithium-Ion Batteries with High Rate Capability journal October 2008
Honeycomb pattern array of vertically standing core-shell nanorods: Its application to Li energy electrodes journal September 2008
Scalable Synthesis of TiO 2 /Graphene Nanostructured Composite with High-Rate Performance for Lithium Ion Batteries journal November 2012
Graphene modified LiFePO4 cathode materials for high power lithium ion batteries journal January 2011
Graphene Enhances Li Storage Capacity of Porous Single-Crystalline Silicon Nanowires journal November 2010
Enhanced reversible lithium storage in a nanosize silicon/graphene composite journal February 2010
Superparamagnetic Fe3O4 nanocrystals@graphene composites for energy storage devices journal January 2011
Fe3O4 nanoparticle-integrated graphene sheets for high-performance half and full lithium ion cells journal January 2011
Mono dispersed SnO2 nanoparticles on both sides of single layer graphene sheets as anode materials in Li-ion batteries journal January 2010
Preparation of SnO 2 -Nanocrystal/Graphene-Nanosheets Composites and Their Lithium Storage Ability journal November 2010
Graphene Anchored with Co3O4 Nanoparticles as Anode of Lithium Ion Batteries with Enhanced Reversible Capacity and Cyclic Performance journal June 2010
Mn3O4−Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries journal October 2010
In situ synthesis of MoS2/graphene nanosheet composites with extraordinarily high electrochemical performance for lithium ion batteries journal January 2011
Nickel ferrite–graphene heteroarchitectures: Toward high-performance anode materials for lithium-ion batteries journal September 2012
Nanohole-structured, iron oxide-decorated and gelatin-functionalized graphene for high rate and high capacity Li-Ion anode journal August 2017
Ever-Increasing Pseudocapacitance in RGO-MnO-RGO Sandwich Nanostructures for Ultrahigh-Rate Lithium Storage journal February 2016
Copper Silicate Hydrate Hollow Spheres Constructed by Nanotubes Encapsulated in Reduced Graphene Oxide as Long-Life Lithium-Ion Battery Anode journal November 2015
Copper silicate nanotubes anchored on reduced graphene oxide for long-life lithium-ion battery journal April 2017
High rate capabilities Fe3O4-based Cu nano-architectured electrodes for lithium-ion battery applications journal June 2006
Template Synthesis of Polypyrrole‐Coated Spinel LiMn2 O 4 Nanotubules and Their Properties as Cathode Active Materials for Lithium Batteries journal January 1997
Rate Capabilities of Nanostructured LiMn2 O 4 Electrodes in Aqueous Electrolyte journal January 2000
Novel Core-Shell Sn-Cu Anodes for Lithium Rechargeable Batteries Prepared by a Redox-Transmetalation Reaction journal October 2010
Ag or Au Nanoparticle-Embedded One-Dimensional Composite TiO 2 Nanofibers Prepared via Electrospinning for Use in Lithium-Ion Batteries journal June 2010
Conductive silver nanowires-fenced carbon cloth fibers-supported layered double hydroxide nanosheets as a flexible and binder-free electrode for high-performance asymmetric supercapacitors journal June 2017
Nickel Nanocone-Array Supported Silicon Anode for High-Performance Lithium-Ion Batteries journal October 2010
Silicon composite thick film electrodeposited on a nickel micro-nanocones hierarchical structured current collector for lithium batteries journal January 2013
High-Rate, Long-Life Ni–Sn Nanostructured Electrodes for Lithium-Ion Batteries journal June 2007
High-Performance Lithium-Ion Battery Anode by Direct Growth of Hierarchical ZnCo 2 O 4 Nanostructures on Current Collectors journal December 2013
Directly grown Co 3 O 4 nanowire arrays on Ni-foam: structural effects of carbon-free and binder-free cathodes for lithium–oxygen batteries journal January 2014
Synthesis of foam-like freestanding Co3O4 nanosheets with enhanced electrochemical activities journal January 2011
Synthesis of Manganese Oxide Electrodes with Interconnected Nanowire Structure as an Anode Material for Rechargeable Lithium Ion Batteries journal December 2005
Ultrafine Nickel-Nanoparticle-Enabled SiO 2 Hierarchical Hollow Spheres for High-Performance Lithium Storage journal November 2017
Using Electroless Deposition for the Preparation of Micron Sized Polymer/Metal Core/Shell Particles and Hollow Metal Spheres journal February 2006
Designing self-standing silicon-copper composite helices as anodes for lithium ion batteries journal August 2016
Cu-Si Nanocable Arrays as High-Rate Anode Materials for Lithium-Ion Batteries journal August 2011
A simple composite protective layer coating that enhances the cycling stability of lithium metal batteries journal June 2015
Porous Co3O4 nanoneedle arrays growing directly on copper foils and their ultrafast charging/discharging as lithium-ion battery anodes journal January 2011
Aluminum-doped lithium nickel cobalt oxide electrodes for high-power lithium-ion batteries journal April 2004
Synthesis and Electrochemical Properties of Vanadium Pentoxide Nanotube Arrays journal March 2005
Synthesis and Electrochemical Properties of Single-Crystal V 2 O 5 Nanorod Arrays by Template-Based Electrodeposition journal July 2004
Growth and Electrochemical Properties of Single-Crystalline V 2 O 5 Nanorod Arrays journal January 2005
Synthesis and electrochemical performance of nano-sized Li4Ti5O12 with double surface modification of Ti(III) and carbon journal January 2009
Mesoporous LiFePO4/C Nanocomposite Cathode Materials for High Power Lithium Ion Batteries with Superior Performance journal September 2010

Cited By (1)


Figures / Tables (12)