The present study demonstrates the development of a supramolecular porous ensemble consisting of hetero‐oligophenylene derivative 6 and Au‐Fe₃O₄ nanodots. Supramolecular assemblies of AIE‐active hetero‐oligophenylene derivative 6 served as reactors for the generation of Au‐Fe₃O₄ nanodots. The as prepared supramolecular ensemble functioned as an efficient recyclable photocatalytic system for C(sp²)−H bond activation of anilines for the construction of quinoline carboxylates. Interestingly, the “dip catalyst” prepared by depositing PTh‐co‐PANI‐6: Au‐Fe₃O₄ nanodots on a filter paper served as a recyclable strip (up to 10 cycles) for C−C/C−N bond formation reaction.

中文翻译：

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将Au-Fe3O4纳米点封装到AIE活性超分子组件中：用于C-C / C-N键形成反应的环境可见光捕集“浸涂”光催化剂

本研究证明了由杂-低聚亚苯基衍生物6和Au-Fe ₃ O ₄纳米点组成的超分子多孔系的发展。AIE活性杂低亚苯基衍生物6的超分子组装体用作生成Au-Fe ₃ O ₄纳米点的反应器。所制备的超分子集合体用作苯胺的C（sp ²）-H键活化的有效可循环光催化体系，用于构造喹啉羧酸酯。有趣的是，通过沉积制备的“浸渍催化剂” PTH的共同-PANI-6：金-铁₃ ö ₄ 滤纸上的纳米点充当可循环利用的条带（最多10个循环），用于CC / CN键形成反应。