A series of cyanato-bridged chain complexes of mixed-valent dinuclear ruthenium(II,III) 3,4,5-trialkoxybenzoates, [Ru₂{3,4,5-(n-C_mH_2m+1O)₃C₆H₂CO₂}₄(OCN)]_n (mOCN) (m = 2–7, 9–18), were synthesized. IR spectra of mOCN showed that the cyanato ligands adopt a μ_1,1-O mode to form zigzag chains. Temperature dependence of magnetic susceptibilities of mOCN showed that the antiferromagnetic interaction between the dinuclear units is strong compared with that of the chlorido-bridged derivatives [Ru₂{3,4,5-(n-C_mH_2m+1O)₃C₆H₂CO₂}₄Cl]_n (mCl). The liquid-crystalline behaviors for mCl with m = 5–18 and mOCN with m = 6–18 were confirmed by polarized-microscopy, X-ray powder diffraction (XRPD), and differential scanning calorimetry (DSC) measurements. The XRPD data confirmed a zigzag form for all samples of mCl. Furthermore, single-crystal X-ray diffraction analyses revealed a chain structure of pentyloxy derivative 5Cl·2nH₂O and a pseudo chain structure of hexyloxy derivative [Ru₂{3,4,5-(n-C₆H₁₃O)₃C₆H₂CO₂}₄(C₂H₅OH)₂][Ru₂{3,4,5-(n-C₆H₁₃O)₃C₆H₂CO₂}₄Cl₂]·2C₂H₅OH (6Cl′·2C₂H₅OH); the XRPD data indicated that the structural change occurs in ambient atmosphere.

中文翻译：

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chlorido-和混合价的双核钌（的氰桥连链复合的磁性和液晶特性II，III）3,4,5- trialkoxybenzoates †

一系列混合价双核钌（II，III）3,4,5-三烷氧基苯甲酸酯[[Ru ₂ {3,4,5-（n -C _m H _{2 m +1} O）₃合成了C ₆ H ₂ CO ₂ } ₄（OCN）_n（m OCN）（m = 2-7，9-18）。的红外光谱米OCN表明，氰配体采用μ _1,1 -O模式形式锯齿链。m OCN磁化率的温度依赖性结果表明，双核单元之间的反铁磁相互作用强于氯桥联衍生物[Ru ₂ {3,4,5-（n -C _m H _{2 m +1} O）₃ C ₆ H ₂ CO ₂ } ₄ Cl] _n（m Cl）。对于液晶行为米氯与米= 5-18和米OCN与米通过偏光显微镜，X射线粉末衍射（XRPD）和差示扫描量热法（DSC）测量确定= 6–18。XRPD数据证实m Cl的所有样品均呈锯齿形。此外，单晶X射线衍射分析显示戊氧基衍生物5Cl ·2 n H ₂ O的链结构和己氧基衍生物[Ru ₂ {3,4,5-（n -C ₆ H ₁₃ O ）₃ C ₆ H ₂ CO ₂ } ₄（C ₂ H ₅ OH）₂ ] [Ru₂ {3,4,5-（ n -C ₆ H ₁₃ O） ₃ C ₆ H ₂ CO ₂ } ₄ Cl ₂ ]·2C ₂ H ₅ OH（ 6Cl' ·2C ₂ H ₅ OH）；XRPD数据表明结构变化发生在周围大气中。