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Effect of TiN addition on the microstructure and mechanical properties of TiB2-FeNi based cermets
Materials Science and Engineering: A ( IF 6.4 ) Pub Date : 2018-11-16 , DOI: 10.1016/j.msea.2018.11.067
Ning Wu , Fengdan Xue , Jianying Wang , Hailin Yang , Fenghua Luo , Jianming Ruan

The TiB2-x vol% TiN-20 vol% (Fe-Ni) system cermets with various volume fraction of TiN were successfully fabricated through gas pressure sintering. The effects of TiN content on the mechanical properties and microstructure of TiB2-based cermets was explored in detail. The microstructure and compositional analyses of TiB2-based cermets were investigated by SEM, EPMA, TEM, and X-ray diffraction. The results shown that only TiB2, TiN and Fe0.64Ni0.36 phases in the TiB2-based cermets, not any other brittle phases such as M2B, M23B6 could be found. The TiB2 grains formed a typical core-rim structure, but the TiN particles didn't. The dominant fracture mode of TiB2-based cermets transformed from intergranular fracture to transgranular fracture as the TiN content increasing from 0 to 25 vol%. Toughening mechanisms of TiB2-based cermets transformed from debonding, crack deflection to crack bridging and crack deflection as the TiN content increasing. The properties of TiB2-based cermets have been greatly enhanced as the TiN content varying from 0 to 25 vol%. The transversal rupture strength, indentation fracture toughness, Vickers hardness, and relative density of TiB2–20 vol% TiN-20 vol% (Fe-Ni) cermet reached up to 1191.12 ± 40 MPa, 18.77 ± 0.40 MPa m1/2, 14.40 ± 0.20 GPa, and 99.74 ± 0.20%, respectively.



中文翻译:

TiN添加对TiB 2 -FeNi基金属陶瓷显微组织和力学性能的影响

通过气压烧结成功地制备了具有不同体积分数的TiN的TiB 2 -x体积%TiN-20体积%(Fe-Ni)系统金属陶瓷。详细探讨了TiN含量对TiB 2基金属陶瓷力学性能和微观结构的影响。通过SEM,EPMA,TEM和X射线衍射研究了基于TiB 2的金属陶瓷的微观结构和组成分析。结果表明,在基于TiB 2的金属陶瓷中,只有TiB 2,TiN和Fe 0.64 Ni 0.36相,没有发现任何其他脆性相,如M 2 B,M 23 B 6。TiB 2晶粒形成了典型的核-边缘结构,但TiN颗粒却没有。随着TiN含量从0到25 vol%的增加,基于TiB 2的金属陶瓷的主要断裂模式从晶间断裂转变为跨晶断裂。随着TiN含量的增加,基于TiB 2的金属陶瓷的增韧机理从脱胶,裂纹变形到裂纹桥接和裂纹变形。当TiN含量从0到25vol%变化时,基于TiB 2的金属陶瓷的性能已大大提高。TiB 2 –20体积%TiN-20体积%(Fe-Ni)金属陶瓷的横向断裂强度,压痕断裂韧性,维氏硬度和相对密度达到1191.12±40 MPa,18.77±0.40 MPa m 1/2,14.40±0.20 GPa和99.74±0.20%。

更新日期:2018-11-16
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