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Low-defectiveness exfoliation of MoS2 nanoparticles and their embedment in hybrid light-emitting polymer nanofibers†
Nanoscale ( IF 6.7 ) Pub Date : 2018-11-15 00:00:00 , DOI: 10.1039/c8nr06294c
Alberto Portone 1 , Luigi Romano , Vito Fasano , Riccardo Di Corato , Andrea Camposeo , Filippo Fabbri , Francesco Cardarelli , Dario Pisignano , Luana Persano
Affiliation  

Molybdenum disulfide (MoS2) has been attracting extraordinary attention for its intriguing optical, electronic and mechanical properties. Here, we demonstrate hybrid, organic–inorganic light-emitting nanofibers based on MoS2 nanoparticle dopants obtained through a simple and inexpensive sonication process in N-methyl-2-pyrrolidone and successfully encapsulate the nanofibers in polymer filaments. The gentle exfoliation method used to produce the MoS2 nanoparticles results in low defectiveness and preserves the stoichiometry. The fabricated hybrid fibers are smooth, uniform and flawless and exhibit bright and continuous light emission. Moreover, the fibers show significant capability for waveguiding self-emitted light along their longitudinal axes. These findings suggest that emissive MoS2 fibers formed by gentle exfoliation are novel and highly promising optical materials for sensing surfaces and photonic circuits.

中文翻译:

MoS2 纳米粒子的低缺陷剥离及其在混合发光聚合物纳米纤维中的嵌入†

二硫化钼(MoS 2)因其令人着迷的光学、电子和机械性能而引起了极大的关注。在这里,我们展示了基于MoS 2纳米粒子掺杂剂的混合有机-无机发光纳米纤维,通过简单且廉价的N-甲基-2-吡咯烷酮超声处理获得,并成功地将纳米纤维封装在聚合物丝中。用于生产MoS 2纳米粒子的温和剥离方法导致低缺陷并保持化学计量。所制造的混合纤维光滑、均匀、无瑕疵,并表现出明亮、连续的光发射。此外,光纤显示出沿着其纵轴波导自发射光的显着能力。这些发现表明,通过温和剥离形成的发射MoS 2纤维是用于传感表面和光子电路的新型且非常有前途的光学材料。
更新日期:2018-11-15
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