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Recent Progress in Polymeric Carbonyl‐Based Electrode Materials for Lithium and Sodium Ion Batteries
Macromolecular Rapid Communications ( IF 4.6 ) Pub Date : 2018-11-09 , DOI: 10.1002/marc.201800565
Kamran Amin 1, 2 , Lijuan Mao 1 , Zhixiang Wei 1, 2
Affiliation  

Advancement in mobile electronics is driving progress in lithium ion batteries. Recently, organic electrode materials have emerged as promising candidates for lithium ion batteries due to their high theoretical capacity, ease of synthesis, versatility of structure, and abundance. Polymerization is a strategy used to overcome the issues associated with small organic molecules for charge storage application. The focus of this review is on the most recent progress in the field of polymeric carbonyl materials for lithium ion batteries (LIBs) and sodium ion batteries (SIBs). Advantages of organic electrode materials, device architecture, and charge storage mechanism are discussed. Challenges associated with carbonyl‐based electrodes and some recent solutions are outlined. Later, a comparison of theoretical capacity, practical capacity, and cyclic life are presented for different carbonyl systems. Capacity‐fading phenomena and structural degradation during charging are discussed where necessary. Some key parameters for the design of flexible batteries are highlighted and an overview of some recent contributions of our group in this field are reported. Finally, some future prospects for researchers in this field are outlined.

中文翻译:

锂和钠离子电池用聚合羰基电极材料的最新进展

移动电子学的进步正在推动锂离子电池的进步。近来,由于有机电极材料的高理论容量,易于合成,结构的通用性和丰富性,已经成为锂离子电池的有希望的候选者。聚合是一种策略,用于克服与小的有机分子在电荷存储应用中相关的问题。这篇综述的重点是用于锂离子电池(LIB)和钠离子电池(SIB)的聚合羰基材料领域的最新进展。讨论了有机电极材料,器件结构和电荷存储机制的优势。概述了与基于羰基的电极相关的挑战以及一些最新的解决方案。后来比较了理论能力,实践能力,给出了不同羰基体系的寿命和循环寿命。必要时讨论容量衰减现象和充电过程中的结构退化。重点介绍了用于柔性电池设计的一些关键参数,并概述了我们小组在该领域的一些近期贡献。最后,概述了该领域研究人员的一些未来前景。
更新日期:2018-11-09
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