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Investigation on removal of NO and Hg0 with different Cu species in Cu-SAPO-34 zeolites
Catalysis Communications ( IF 3.7 ) Pub Date : 2018-10-30 , DOI: 10.1016/j.catcom.2018.10.019
Yu Wang , Wenzhe Si , Yue Peng , Junhua Li

A series of Cu-SAPO-34 zeolites with different Cu contents were prepared by one-pot synthesis method. The NH3-SCR performance and the oxidation of elemental mercury (Hg0) efficiency over the Cu-SAPO-34 samples were tested respectively. With the increase of Cu loadings, the amount of Cu2+ and CuO were both increased, wherein the former promoted SCR reaction and the latter accelerated the Hg0 oxidation. What's more, the ratio of Cu2+/CuO was also increased. The NO conversion rate and Hg0 removal efficiency could be over 80% on the high Cu catalyst at 150–300 °C.



中文翻译:

Cu-SAPO-34沸石中不同Cu种类脱除NO和Hg 0的研究

通过一锅法合成了一系列不同Cu含量的Cu-SAPO-34沸石。分别测试了Cu-SAPO-34样品的NH3-SCR性能和元素汞(Hg 0)的氧化效率。随着Cu含量的增加,Cu 2+和CuO的含量均增加,其中前者促进了SCR反应,而后者促进了Hg 0的氧化。而且,Cu 2+ / CuO的比例也增加了。在150–300°C的高铜催化剂上,NO转化率和Hg 0去除效率可能超过80%。

更新日期:2018-10-30
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