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Co-catalysis of corncob with dilute formic acid plus solid acid SO42−/SnO2-montmorillonite under the microwave for enhancing the biosynthesis of furfuralcohol
Catalysis Communications ( IF 3.7 ) Pub Date : 2018-10-22 , DOI: 10.1016/j.catcom.2018.10.021
Yibo Huang , Xiaolong Liao , Yuying Deng , Yucai He

In this study, chemo-enzymatic synthesis of furfuralcohol (FOL) from corncob was attempted by sequential catalysis of HCOOH (1.0 wt%)-assisted solid acid SO42−/SnO2-montmorillonite (2.0 wt%) at 180 °C for 10 min under microwave (600 W) and recombinant Escherichia coli CCZU-T15 whole-cells bioreduction for 4 h at 30 °C and pH 6.5. Furfural was obtained at 40.2% yield, and it (77.8 mM) could be completely biotransformed to FOL. Moreover, efficient biocatalyst recycling was achieved with immobilized cells. Clearly, this strategy has potential application for the effective synthesis of FOL from corncob.



中文翻译:

微波作用下玉米芯与稀甲酸加固体酸SO 4 2- / SnO 2-蒙脱土共催化增强糠醇的生物合成

在这项研究中,尝试通过在180°C下连续催化HCOOH(1.0 wt%)辅助固体酸SO 4 2- / SnO 2-蒙脱石(2.0 wt%)从玉米芯化学合成糠醛(FOL)。在微波(600 W)和重组大肠杆菌CCZU-T15全细胞生物还原作用下于30°C和pH 6.5下进行10 min还原4 h。以40.2%的收率获得糠醛,并且糠醛(77.8 mM)可以完全生物转化为FOL。而且,利用固定化的细胞实现了有效的生物催化剂回收。显然,该策略对于从玉米芯有效合成FOL具有潜在的应用前景。

更新日期:2018-10-22
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