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1-Oxo-2,2,6,6-tetramethylpiperidinium bromide converts α-H N,N-dialkylhydroxylamines to nitrones via a two-electron oxidation mechanism.
Scientific Reports ( IF 4.6 ) Pub Date : 2018-Oct-17 , DOI: 10.1038/s41598-018-33639-w
Anastas D. Stoyanovsky , Detcho A. Stoyanovsky

Herein we provide experimental proof that 1-oxo-2,2,6,6-tetramethylpiperidinium bromide converts α-H N,N-dialkylhydroxylamines to nitrones via a two-electron oxidation mechanism. The reactions reported are rapid, proceed under mild conditions, and afford nitrones in excellent yields.

中文翻译:

1-Oxo-2,2,6,6-四甲基哌啶溴化物通过两电子氧化机理将α-HN,N-二烷基羟胺转化为硝酮。

本文中,我们提供了实验证明,即1-oxo-2,2,6,6-四甲基溴化溴化物通过两电子氧化机理将α-HN,N-二烷基羟胺转化为硝酮。报道的反应是快速的,在温和的条件下进行,并以优异的产率提供了硝基。
更新日期:2018-10-17
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