Iron(III)-catalyzed radical α,β-aminophosphinoylation of styrenes with diphenylphosphine oxides and anilines,Organic & Biomolecular Chemistry

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Iron(III)-catalyzed radical α,β-aminophosphinoylation of styrenes with diphenylphosphine oxides and anilines
Organic & Biomolecular Chemistry ( IF 3.2 ) Pub Date : 2018-10-15 , DOI: 10.1039/c8ob02151a
Yu Wang _{1,

2,

3,

4} , Wei Wang _{1,

2,

3,

4} , Ruyun Tang _{1,

2,

3,

4} , Zhenhua Liu _{4,

5,

6,

7,

8} , Weihua Tao _{1,

2,

3,

4} , Zhongxue Fang _{1,

2,

3,

4}

Affiliation

A Fe-catalyzed highly regioselective α,β-difunctionalization of vinylarenes with diphenylphosphine oxides and anilines is disclosed, in which α,β-aminophosphinoylation is efficiently and conveniently constructed under mild conditions with good functional compatibility and a broad substrate scope. The control experiments have revealed a radical reaction pathway.

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