Highly concentrated single-chain atomic crystal LiMo3Se3 solution using ion-exchange chromatography†,Chemical Communications

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Highly concentrated single-chain atomic crystal LiMo3Se3 solution using ion-exchange chromatography†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-10-15 00:00:00 , DOI: 10.1039/c8cc06306k
Sudong Chae _{1,

2,

3,

4} , Seungbae Oh _{1,

2,

3,

4} , Akhtar J. Siddiqa _{1,

2,

3,

4} , Kyung Hwan Choi _{2,

3,

4,

5} , Weon-Gyu Lee _{2,

3,

4,

6} , Woo-Sung Jang _{2,

3,

4,

7} , Joo Song Lee _{3,

4,

8,

9} , Young-Min Kim _{2,

3,

4,

7,

10} , Joonsuk Huh _{2,

3,

4,

6} , Soo Min Kim _{3,

4,

8,

9} , Jae-Young Choi _{1,

2,

3,

4,

5}

Affiliation

Ion-exchange chromatography can be used to effectively replace the lithium ion of LiMo₃Se₃ with a proton. The enlargement of the Stern layer distance caused by this ion exchange improves the dispersibility of (Mo₃Se₃⁻)_∞ chains and also prevents the re-bundling and aggregation of nanowires in aqueous solutions, even at high concentrations (1 mg mL⁻¹).

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