This study reported integration of Ni–P/TiO₂ incorporated structure on silk textiles to produce a flexible, highly reliable, and photocatalytic composite material toward applications in functional wearable devices. Supercritical carbon dioxide (Sc–CO₂) promoted electroless plating was utilized to codeposit photocatalytic TiO₂ and electrically conductive Ni–P metallization layer on silk textile. Silk was chosen as the substrate for its flexibility and stretchability. Ni–P was utilized due to its high corrosion resistance, electrical conductivity, and high wear resistance. TiO₂ was selected for its photocatalytic activity and acting as a reinforcement filler to fulfill requirements for applications in wearable devices. Surface morphology, composition, crystal structure, electrical resistance, corrosion resistance, adhesive test, and photocatalytic activity assessments were conducted to evaluate the practicability for wearable photocatalytic devices. With the assistance of sc–CO₂, palladium (II) acetylacetonate catalyst was successfully embedded into the silk substrate at around 330 nm in depth. The coatings on the silk were confirmed to be amorphous Ni–P phase and TiO₂ anatase phase. Uniform Ni–P/TiO₂ composite layer with strong adherence was successfully co–deposited on the silk textile. Ni–P/TiO₂ composite layer deposited with 30 g/L of TiO₂ (critical concentration) in the electrolyte showed higher corrosion resistance while comparing to those of TiO₂–free specimen. The Ni–P/TiO₂ composite layer deposited with the critical concentration of TiO₂ in the electrolyte performed the highest photocatalytic activity.

这项研究报道了将Ni–P / TiO ₂掺入的结构整合到丝织物上，从而生产出一种柔性，高度可靠且光催化的复合材料，以用于功能性可穿戴设备。超临界二氧化碳（Sc–CO ₂）促进的化学镀被用于在丝织物上共沉积光催化TiO ₂和导电的Ni–P金属化层。丝绸因其柔韧性和可拉伸性而被选为基材。使用Ni-P的原因在于其高耐腐蚀性，导电性和高耐磨性。二氧化钛₂选择它的原因是其具有光催化活性，并可以充当补强填充剂，以满足可穿戴设备中的应用要求。进行了表面形态，组成，晶体结构，电阻，耐腐蚀性，粘合力测试和光催化活性评估，以评估可穿戴光催化装置的实用性。在sc-CO ₂的协助下，乙酰丙酮钯（II）催化剂成功地以约330 nm的深度嵌入到丝绸基质中。丝绸上的涂层被证实为非晶态Ni-P相和TiO ₂锐钛矿相。具有强附着力的均匀Ni-P / TiO ₂复合层成功地共沉积在丝织物上。Ni–P / TiO ₂与不含TiO _2的样品相比，在电解质中沉积有30​​ g / L TiO ₂（临界浓度）的复合层显示出更高的耐腐蚀性。在电解质中以临界浓度TiO ₂沉积的Ni-P / TiO ₂复合层表现出最高的光催化活性。