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First total synthesis of Brevipolide N and total synthesis of Brevipolide M
Tetrahedron Letters ( IF 1.8 ) Pub Date : 2018-10-11 , DOI: 10.1016/j.tetlet.2018.10.018 Kasa Shiva Raju , Gowravaram Sabitha
中文翻译:
布雷维波利德N的首次全合成和布雷维波利德M的全合成
更新日期:2018-10-11
Tetrahedron Letters ( IF 1.8 ) Pub Date : 2018-10-11 , DOI: 10.1016/j.tetlet.2018.10.018 Kasa Shiva Raju , Gowravaram Sabitha
The First total Synthesis of Brevipolide N and total Synthesis Brevipolide M have been accomplished from commercially available d-Mannitol. The key features of the syntheses are the use of Horner–Wadsworth–Emmons olefination, Noyori reduction, Acid catalyzed epoxide opening and Lindlars reaction.
中文翻译:
布雷维波利德N的首次全合成和布雷维波利德M的全合成
Brevipolide N的第一个全合成和Brevipolide M的全合成已从市售d-甘露糖醇中完成。合成的关键特征是霍纳-沃兹沃思-埃蒙斯烯烃的使用,Noyori还原,酸催化的环氧化物开口和Lindlars反应。