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Dehydrogenative Aromatization and Sulfonylation of Pyrrolidines: Orthogonal Reactivity in Photoredox Catalysis
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2018-10-11 , DOI: 10.1002/anie.201808427 Krishnamoorthy Muralirajan 1 , Rajesh Kancherla 1 , Magnus Rueping 1, 2
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2018-10-11 , DOI: 10.1002/anie.201808427 Krishnamoorthy Muralirajan 1 , Rajesh Kancherla 1 , Magnus Rueping 1, 2
Affiliation
Oxidative dehydrogenative aromatization and selective sulfonylation reactions of N‐heterocycles under visible‐light photoredox catalysis were established. The mild reaction conditions make this approach an appealing and versatile strategy to functionalize/oxidize pyrrolidines whereby arylsulfonyl chlorides were identified to be both catalyst regeneration and sulfonylation reagents.
中文翻译:
吡咯烷的脱氢芳香化和磺酰化:在光氧化还原催化中的正交反应性。
建立了可见光氧化还原催化下N-杂环的氧化脱氢芳构化和选择性磺酰化反应。温和的反应条件使该方法成为使吡咯烷官能化/氧化的引人入胜且通用的策略,由此鉴定出芳基磺酰氯既是催化剂再生又是磺酰化试剂。
更新日期:2018-10-11
中文翻译:
吡咯烷的脱氢芳香化和磺酰化:在光氧化还原催化中的正交反应性。
建立了可见光氧化还原催化下N-杂环的氧化脱氢芳构化和选择性磺酰化反应。温和的反应条件使该方法成为使吡咯烷官能化/氧化的引人入胜且通用的策略,由此鉴定出芳基磺酰氯既是催化剂再生又是磺酰化试剂。